Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes
Many battery electrodes contain ensembles of nanoparticles that phase-separate on (de)intercalation. In such electrodes, the fraction of actively intercalating particles directly impacts cycle life: a vanishing population concentrates the current in a small number of particles, leading to current ho...
Main Authors: | Li, Yiyang, El Gabaly, Farid, Bartelt, Norman C., Sugar, Joshua D., Fenton, Kyle R., Cogswell, Daniel A., Kilcoyne, A. L. David, Tyliszczak, Tolek, Chueh, William C., Ferguson, Todd Richard, Smith, Raymond Barrett, Bazant, Martin Z |
---|---|
Other Authors: | Massachusetts Institute of Technology. Department of Chemical Engineering |
Format: | Article |
Language: | en_US |
Published: |
Nature Publishing Group
2017
|
Online Access: | http://hdl.handle.net/1721.1/110915 https://orcid.org/0000-0003-2421-6781 |
Similar Items
-
Phase Separation Dynamics in Isotropic Ion-Intercalation Particles
by: Zeng, Yi, et al.
Published: (2014) -
Intercalation Kinetics in Multiphase-Layered Materials
by: Smith, Raymond Barrett, et al.
Published: (2018) -
Size-dependent phase morphologies in LiFePO4 battery particles
by: Cogswell, Daniel Aaron, et al.
Published: (2020) -
Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles
by: Lim, J., et al.
Published: (2017) -
Mathematical modeling of lithium-ion intercalation particles and their electrochemical dynamics
by: Zeng, Yi, Ph. D. Massachusetts Institute of Technology
Published: (2015)