Grand Challenges and Future Opportunities for Metal–Organic Frameworks
Metal-organic frameworks (MOFs) allow compositional and structural diversity beyond conventional solid-state materials. Continued interest in the field is justified by potential applications of exceptional breadth, ranging from gas storage and separation, which takes advantage of the inherent pores...
| Main Authors: | , , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Published: |
American Chemical Society (ACS)
2018
|
| Online Access: | http://hdl.handle.net/1721.1/113273 https://orcid.org/0000-0002-9890-1346 https://orcid.org/0000-0002-6577-1821 https://orcid.org/0000-0002-1262-1264 |
| _version_ | 1811080718553448448 |
|---|---|
| author | Hendon, Christopher H Rieth, Adam Joseph Korzynski, Maciej Damian Dinca, Mircea |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Hendon, Christopher H Rieth, Adam Joseph Korzynski, Maciej Damian Dinca, Mircea |
| author_sort | Hendon, Christopher H |
| collection | MIT |
| description | Metal-organic frameworks (MOFs) allow compositional and structural diversity beyond conventional solid-state materials. Continued interest in the field is justified by potential applications of exceptional breadth, ranging from gas storage and separation, which takes advantage of the inherent pores and their volume, to electronic applications, which requires precise control of electronic structure. In this Outlook we present some of the pertinent challenges that MOFs face in their conventional implementations, as well as opportunities in less traditional areas. Here the aim is to discuss select design concepts and future research goals that emphasize nuances relevant to this class of materials as a whole. Particular emphasis is placed on synthetic aspects, as they influence the potential for MOFs in gas separation, electrical conductivity, and catalytic applications. |
| first_indexed | 2024-09-23T11:35:40Z |
| format | Article |
| id | mit-1721.1/113273 |
| institution | Massachusetts Institute of Technology |
| last_indexed | 2024-09-23T11:35:40Z |
| publishDate | 2018 |
| publisher | American Chemical Society (ACS) |
| record_format | dspace |
| spelling | mit-1721.1/1132732022-09-27T20:37:18Z Grand Challenges and Future Opportunities for Metal–Organic Frameworks Hendon, Christopher H Rieth, Adam Joseph Korzynski, Maciej Damian Dinca, Mircea Massachusetts Institute of Technology. Department of Chemistry Hendon, Christopher H Rieth, Adam Joseph Korzynski, Maciej Damian Dinca, Mircea Metal-organic frameworks (MOFs) allow compositional and structural diversity beyond conventional solid-state materials. Continued interest in the field is justified by potential applications of exceptional breadth, ranging from gas storage and separation, which takes advantage of the inherent pores and their volume, to electronic applications, which requires precise control of electronic structure. In this Outlook we present some of the pertinent challenges that MOFs face in their conventional implementations, as well as opportunities in less traditional areas. Here the aim is to discuss select design concepts and future research goals that emphasize nuances relevant to this class of materials as a whole. Particular emphasis is placed on synthetic aspects, as they influence the potential for MOFs in gas separation, electrical conductivity, and catalytic applications. United States. Department of Energy (Award DE-SC0001088) United States. Department of Energy (Award DE-SC0006937) National Science Foundation (U.S.) (Award DMR-1452612) National Science Foundation (U.S.) (Grant ACI-1053575) 2018-01-23T16:00:52Z 2018-01-23T16:00:52Z 2017-06 2017-05 2018-01-19T19:15:51Z Article http://purl.org/eprint/type/JournalArticle 2374-7943 2374-7951 http://hdl.handle.net/1721.1/113273 Hendon, Christopher H. et al. “Grand Challenges and Future Opportunities for Metal–Organic Frameworks.” ACS Central Science 3, 6 (June 2017): 554–563 © 2017 American Chemical Society https://orcid.org/0000-0002-9890-1346 https://orcid.org/0000-0002-6577-1821 https://orcid.org/0000-0002-1262-1264 http://dx.doi.org/10.1021/ACSCENTSCI.7B00197 ACS Central Science Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) ACS |
| spellingShingle | Hendon, Christopher H Rieth, Adam Joseph Korzynski, Maciej Damian Dinca, Mircea Grand Challenges and Future Opportunities for Metal–Organic Frameworks |
| title | Grand Challenges and Future Opportunities for Metal–Organic Frameworks |
| title_full | Grand Challenges and Future Opportunities for Metal–Organic Frameworks |
| title_fullStr | Grand Challenges and Future Opportunities for Metal–Organic Frameworks |
| title_full_unstemmed | Grand Challenges and Future Opportunities for Metal–Organic Frameworks |
| title_short | Grand Challenges and Future Opportunities for Metal–Organic Frameworks |
| title_sort | grand challenges and future opportunities for metal organic frameworks |
| url | http://hdl.handle.net/1721.1/113273 https://orcid.org/0000-0002-9890-1346 https://orcid.org/0000-0002-6577-1821 https://orcid.org/0000-0002-1262-1264 |
| work_keys_str_mv | AT hendonchristopherh grandchallengesandfutureopportunitiesformetalorganicframeworks AT riethadamjoseph grandchallengesandfutureopportunitiesformetalorganicframeworks AT korzynskimaciejdamian grandchallengesandfutureopportunitiesformetalorganicframeworks AT dincamircea grandchallengesandfutureopportunitiesformetalorganicframeworks |