New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene
Three types of analyses: generalized conventional spectroscopic analysis, statistical analysis, and hierarchical analysis, by which we aim to extract dynamical information from the complex spectrum of small polyatomic molecules are reviewed by referring to recent studies on vibrationally highly exci...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
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Hindawi Publishing Corporation
2018
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| Online Access: | http://hdl.handle.net/1721.1/114845 https://orcid.org/0000-0002-7609-4205 |
| _version_ | 1811090041411207168 |
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| author | Yamanouchi, Kaoru Miyawaki, Jun Tsuchiya, Soji Jonas, David M. Field, Robert W |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Yamanouchi, Kaoru Miyawaki, Jun Tsuchiya, Soji Jonas, David M. Field, Robert W |
| author_sort | Yamanouchi, Kaoru |
| collection | MIT |
| description | Three types of analyses: generalized conventional spectroscopic analysis, statistical analysis, and hierarchical analysis, by which we aim to extract dynamical information from the complex spectrum of small polyatomic molecules are reviewed by referring to recent studies on vibrationally highly excited acetylene. A convolution analysis, one type of hierarchical analysis, is performed on the dispersed fluorescence spectrum of acetylene to demonstrate its practical applicability. Based on previous studies, as well as on the convolution analysis, a systematic and efficient procedure to treat such complex spectra is discussed. |
| first_indexed | 2024-09-23T14:31:08Z |
| format | Article |
| id | mit-1721.1/114845 |
| institution | Massachusetts Institute of Technology |
| language | English |
| last_indexed | 2024-09-23T14:31:08Z |
| publishDate | 2018 |
| publisher | Hindawi Publishing Corporation |
| record_format | dspace |
| spelling | mit-1721.1/1148452022-10-01T21:36:00Z New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene Yamanouchi, Kaoru Miyawaki, Jun Tsuchiya, Soji Jonas, David M. Field, Robert W Massachusetts Institute of Technology. Department of Chemistry Field, Robert W Three types of analyses: generalized conventional spectroscopic analysis, statistical analysis, and hierarchical analysis, by which we aim to extract dynamical information from the complex spectrum of small polyatomic molecules are reviewed by referring to recent studies on vibrationally highly excited acetylene. A convolution analysis, one type of hierarchical analysis, is performed on the dispersed fluorescence spectrum of acetylene to demonstrate its practical applicability. Based on previous studies, as well as on the convolution analysis, a systematic and efficient procedure to treat such complex spectra is discussed. 2018-04-20T22:45:19Z 2018-04-20T22:45:19Z 1994-01 1993-05 2018-03-01T08:04:45Z Article http://purl.org/eprint/type/JournalArticle 0278-6273 1476-3516 http://hdl.handle.net/1721.1/114845 Yamanouchi, Kaoru, et al. “New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene.” Laser Chemistry, vol. 14, no. 1–3, 1994, pp. 183–90. © 1994 Hindawi Publishing Corporation https://orcid.org/0000-0002-7609-4205 en https://doi.org/10.1155/1994/34542 Laser Chemistry Creative Commons Attribution http://creativecommons.org/licenses/by/3.0/ Copyright © 1994 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. application/pdf Hindawi Publishing Corporation Hindawi Publishing Corporation |
| spellingShingle | Yamanouchi, Kaoru Miyawaki, Jun Tsuchiya, Soji Jonas, David M. Field, Robert W New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene |
| title | New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene |
| title_full | New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene |
| title_fullStr | New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene |
| title_full_unstemmed | New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene |
| title_short | New Scheme for Extracting Molecular Dynamics from Spectra: Case Study on Vibrationally Highly Excited Acetylene |
| title_sort | new scheme for extracting molecular dynamics from spectra case study on vibrationally highly excited acetylene |
| url | http://hdl.handle.net/1721.1/114845 https://orcid.org/0000-0002-7609-4205 |
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