Smectic A mesophases from luminescent sandic platinum(II) mesogens
Square planar platinum(II) thienyl pyridyl complexes with board-shaped structures assemble into lamellar (SmA) liquid crystal phases at elevated temperatures. Liquid crystals of this type are expected to have stronger biaxial correlations than typical calamitic mesogens. The mesophase stability impr...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | en_US |
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Taylor & Francis
2018
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| Online Access: | http://hdl.handle.net/1721.1/115093 https://orcid.org/0000-0001-7153-6898 https://orcid.org/0000-0003-2769-3321 |
| _version_ | 1810976147518783488 |
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| author | Venkatesan, Koushik Kouwer, Paul H. J. Swager, Timothy M. Krikorian, Markrete Voll, Constantin-Chri Alexander Yoon, Maryam A. Swager, Timothy M |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Venkatesan, Koushik Kouwer, Paul H. J. Swager, Timothy M. Krikorian, Markrete Voll, Constantin-Chri Alexander Yoon, Maryam A. Swager, Timothy M |
| author_sort | Venkatesan, Koushik |
| collection | MIT |
| description | Square planar platinum(II) thienyl pyridyl complexes with board-shaped structures assemble into lamellar (SmA) liquid crystal phases at elevated temperatures. Liquid crystals of this type are expected to have stronger biaxial correlations than typical calamitic mesogens. The mesophase stability improves with decreasing alkyl chain lengths with C₈H₁₇ having the widest range of stability. All complexes are luminescent in solution. |
| first_indexed | 2024-09-23T08:50:39Z |
| format | Article |
| id | mit-1721.1/115093 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T08:50:39Z |
| publishDate | 2018 |
| publisher | Taylor & Francis |
| record_format | dspace |
| spelling | mit-1721.1/1150932022-09-30T11:40:30Z Smectic A mesophases from luminescent sandic platinum(II) mesogens Venkatesan, Koushik Kouwer, Paul H. J. Swager, Timothy M. Krikorian, Markrete Voll, Constantin-Chri Alexander Yoon, Maryam A. Swager, Timothy M Massachusetts Institute of Technology. Department of Chemistry Swager, Timothy M Krikorian, Markrete Voll, Constantin-Chri Alexander Yoon, Maryam A. Swager, Timothy M Square planar platinum(II) thienyl pyridyl complexes with board-shaped structures assemble into lamellar (SmA) liquid crystal phases at elevated temperatures. Liquid crystals of this type are expected to have stronger biaxial correlations than typical calamitic mesogens. The mesophase stability improves with decreasing alkyl chain lengths with C₈H₁₇ having the widest range of stability. All complexes are luminescent in solution. National Science Foundation (U.S.) (Grant DMR-1410718) 2018-04-30T16:45:29Z 2018-04-30T16:45:29Z 2016-06 2016-04 Article http://purl.org/eprint/type/JournalArticle 0267-8292 1366-5855 http://hdl.handle.net/1721.1/115093 Krikorian, Markrete et al. “Smectic A Mesophases from Luminescent Sandic platinum(II) Mesogens.” Liquid Crystals 43, 12 (June 2016): 1709–1713 © 2016 Informa UK Limited, trading as Taylor & Francis Group https://orcid.org/0000-0001-7153-6898 https://orcid.org/0000-0003-2769-3321 en_US https://doi.org/10.1080/02678292.2016.1200679 Liquid Crystals Creative Commons Attribution-Noncommercial-Share Alike http://creativecommons.org/licenses/by-nc-sa/4.0/ application/pdf Taylor & Francis Prof. Swager via Erja Kajosalo |
| spellingShingle | Venkatesan, Koushik Kouwer, Paul H. J. Swager, Timothy M. Krikorian, Markrete Voll, Constantin-Chri Alexander Yoon, Maryam A. Swager, Timothy M Smectic A mesophases from luminescent sandic platinum(II) mesogens |
| title | Smectic A mesophases from luminescent sandic platinum(II) mesogens |
| title_full | Smectic A mesophases from luminescent sandic platinum(II) mesogens |
| title_fullStr | Smectic A mesophases from luminescent sandic platinum(II) mesogens |
| title_full_unstemmed | Smectic A mesophases from luminescent sandic platinum(II) mesogens |
| title_short | Smectic A mesophases from luminescent sandic platinum(II) mesogens |
| title_sort | smectic a mesophases from luminescent sandic platinum ii mesogens |
| url | http://hdl.handle.net/1721.1/115093 https://orcid.org/0000-0001-7153-6898 https://orcid.org/0000-0003-2769-3321 |
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