Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions
A new calix[6]azacryptand ligand has been prepared in six steps starting from 1,3,5-trismethoxycalix[6]arene. An X-ray study shows that this ligand has a sterically protected tren-based binding site at the bottom of a polyaromatic bowl and ether sites around its rim. It binds Zn²⁺ to give a complex...
| Main Authors: | , , , , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | en_US |
| Published: |
American Chemical Society (ACS)
2018
|
| Online Access: | http://hdl.handle.net/1721.1/115119 https://orcid.org/0000-0003-2933-8665 https://orcid.org/0000-0001-5827-3552 https://orcid.org/0000-0001-6530-3852 |
| _version_ | 1811086422751313920 |
|---|---|
| author | Zahim, Sara Evano, Gwilherm Jabin, Ivan Wickramasinghe Weerakkodi Appuhamilage, Lasantha A Schrock, Richard Royce Mueller, Peter |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Zahim, Sara Evano, Gwilherm Jabin, Ivan Wickramasinghe Weerakkodi Appuhamilage, Lasantha A Schrock, Richard Royce Mueller, Peter |
| author_sort | Zahim, Sara |
| collection | MIT |
| description | A new calix[6]azacryptand ligand has been prepared in six steps starting from 1,3,5-trismethoxycalix[6]arene. An X-ray study shows that this ligand has a sterically protected tren-based binding site at the bottom of a polyaromatic bowl and ether sites around its rim. It binds Zn²⁺ to give a complex in which zinc is in a trigonal bipyramidal geometry with a water bound in one apical position and two additional hydrogen-bonded waters that fill the calixarene cavity. |
| first_indexed | 2024-09-23T13:25:40Z |
| format | Article |
| id | mit-1721.1/115119 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T13:25:40Z |
| publishDate | 2018 |
| publisher | American Chemical Society (ACS) |
| record_format | dspace |
| spelling | mit-1721.1/1151192022-09-28T14:08:51Z Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions Zahim, Sara Evano, Gwilherm Jabin, Ivan Wickramasinghe Weerakkodi Appuhamilage, Lasantha A Schrock, Richard Royce Mueller, Peter Massachusetts Institute of Technology. Department of Chemistry Schrock, Richard Royce Wickramasinghe Weerakkodi Appuhamilage, Lasantha A Schrock, Richard Royce Mueller, Peter A new calix[6]azacryptand ligand has been prepared in six steps starting from 1,3,5-trismethoxycalix[6]arene. An X-ray study shows that this ligand has a sterically protected tren-based binding site at the bottom of a polyaromatic bowl and ether sites around its rim. It binds Zn²⁺ to give a complex in which zinc is in a trigonal bipyramidal geometry with a water bound in one apical position and two additional hydrogen-bonded waters that fill the calixarene cavity. United States. Department of Energy (Grant DE-SC0013307) 2018-05-01T13:51:24Z 2018-05-01T13:51:24Z 2016-02 2016-04 Article http://purl.org/eprint/type/JournalArticle 1523-7060 1523-7052 http://hdl.handle.net/1721.1/115119 Zahim, Sara et al. “Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions.” Organic Letters 18, 7 (March 2016): 1570–1573 © 2016 American Chemical Society https://orcid.org/0000-0003-2933-8665 https://orcid.org/0000-0001-5827-3552 https://orcid.org/0000-0001-6530-3852 en_US http://dx.doi.org/10.1021/acs.orglett.6b00410 Organic Letters Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) Prof. Schrock via Erja Kajosalo |
| spellingShingle | Zahim, Sara Evano, Gwilherm Jabin, Ivan Wickramasinghe Weerakkodi Appuhamilage, Lasantha A Schrock, Richard Royce Mueller, Peter Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions |
| title | Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions |
| title_full | Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions |
| title_fullStr | Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions |
| title_full_unstemmed | Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions |
| title_short | Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions |
| title_sort | calix 6 azacryptand ligand with a sterically protected tren based coordination site for metal ions |
| url | http://hdl.handle.net/1721.1/115119 https://orcid.org/0000-0003-2933-8665 https://orcid.org/0000-0001-5827-3552 https://orcid.org/0000-0001-6530-3852 |
| work_keys_str_mv | AT zahimsara calix6azacryptandligandwithastericallyprotectedtrenbasedcoordinationsiteformetalions AT evanogwilherm calix6azacryptandligandwithastericallyprotectedtrenbasedcoordinationsiteformetalions AT jabinivan calix6azacryptandligandwithastericallyprotectedtrenbasedcoordinationsiteformetalions AT wickramasingheweerakkodiappuhamilagelasanthaa calix6azacryptandligandwithastericallyprotectedtrenbasedcoordinationsiteformetalions AT schrockrichardroyce calix6azacryptandligandwithastericallyprotectedtrenbasedcoordinationsiteformetalions AT muellerpeter calix6azacryptandligandwithastericallyprotectedtrenbasedcoordinationsiteformetalions |