A Biphilic Phosphetane Catalyzes N–N Bond-Forming Cadogan Heterocyclization via P[superscript III]/P[superscript V]═O Redox Cycling

A Biphilic Phosphetane Catalyzes N–N Bond-Forming Cadogan Heterocyclization via P[superscript III]/P[superscript V]═O Redox Cycling

A small-ring phosphacycle, 1,2,2,3,4,4-hexamethylphosphetane, is found to catalyze deoxygenative N-N bond-forming Cadogan h eterocyclization of o-nitrobenzaldimines, o-nitroazobenzenes, and related substrates in the presence of hydrosilane terminal reductant. The reaction provides a chemoselective c...

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Bibliographic Details
Main Authors:	Putnik, Rachel A., Nykaza, Trevor Vincent, Harrison, Tyler Steven, Ghosh, Avipsa, Radosevich, Alexander T.
Other Authors:	Massachusetts Institute of Technology. Department of Chemistry
Format:	Article
Published:	American Chemical Society (ACS) 2018
Online Access:	http://hdl.handle.net/1721.1/116319 https://orcid.org/0000-0002-7683-2984 https://orcid.org/0000-0003-3786-0453

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