Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands
In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts...
| 主要な著者: | , |
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| その他の著者: | |
| フォーマット: | 論文 |
| 出版事項: |
American Chemical Society (ACS)
2018
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| オンライン･アクセス: | http://hdl.handle.net/1721.1/116337 https://orcid.org/0000-0002-9049-6227 https://orcid.org/0000-0003-3875-4775 |
| 要約: | In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts, particularly in the case of the bulkiest biarylphosphine ligands, for which palladacycle-based precatalysts do not readily form. The precatalysts described herein are easily prepared and stable to long-term storage under air. |
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