Fracture Mechanisms in Organic-Rich Shales: Role of Kerogen

In this work we study role of kerogen in the fracture properties of organic-rich shales and, in particular, in the ductility of shales. The presence of kerogen and clays in shale is known to increase the ductility. We propose here a multiscale approach to develop a fine understanding of shale ductil...

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Main Authors: Brochard, Laurent, Hantal, Gyorgy Miklos, Laubie, Hadrien H, Ulm, Franz-Josef, Pellenq, Roland Jm
Other Authors: Massachusetts Institute of Technology. Department of Civil and Environmental Engineering
Format: Article
Published: American Society of Civil Engineers (ASCE) 2018
Online Access:http://hdl.handle.net/1721.1/117479
https://orcid.org/0000-0002-7089-8069
https://orcid.org/0000-0001-5559-4190
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author Brochard, Laurent
Hantal, Gyorgy Miklos
Laubie, Hadrien H
Ulm, Franz-Josef
Pellenq, Roland Jm
author2 Massachusetts Institute of Technology. Department of Civil and Environmental Engineering
author_facet Massachusetts Institute of Technology. Department of Civil and Environmental Engineering
Brochard, Laurent
Hantal, Gyorgy Miklos
Laubie, Hadrien H
Ulm, Franz-Josef
Pellenq, Roland Jm
author_sort Brochard, Laurent
collection MIT
description In this work we study role of kerogen in the fracture properties of organic-rich shales and, in particular, in the ductility of shales. The presence of kerogen and clays in shale is known to increase the ductility. We propose here a multiscale approach to develop a fine understanding of shale ductility from the molecular scale. We develop and validate a methodology at the molecular scale that can capture the toughness and ductility of a material. We apply this methodology successfully to a silica polymorph and to a kerogen analog, and we confirm the significant ductility of kerogen. Interestingly the silica-kerogen interface exhibits a similar ductility, which is central for the properties of the heterogeneous shale. Finally, we consider a tentative upscaling considering the pull out phenomenon as a likely mechanism of fracture of the shale.
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spelling mit-1721.1/1174792022-09-23T13:23:52Z Fracture Mechanisms in Organic-Rich Shales: Role of Kerogen Brochard, Laurent Hantal, Gyorgy Miklos Laubie, Hadrien H Ulm, Franz-Josef Pellenq, Roland Jm Massachusetts Institute of Technology. Department of Civil and Environmental Engineering Hantal, Gyorgy Miklos Laubie, Hadrien H Ulm, Franz-Josef Pellenq, Roland Jm In this work we study role of kerogen in the fracture properties of organic-rich shales and, in particular, in the ductility of shales. The presence of kerogen and clays in shale is known to increase the ductility. We propose here a multiscale approach to develop a fine understanding of shale ductility from the molecular scale. We develop and validate a methodology at the molecular scale that can capture the toughness and ductility of a material. We apply this methodology successfully to a silica polymorph and to a kerogen analog, and we confirm the significant ductility of kerogen. Interestingly the silica-kerogen interface exhibits a similar ductility, which is central for the properties of the heterogeneous shale. Finally, we consider a tentative upscaling considering the pull out phenomenon as a likely mechanism of fracture of the shale. 2018-08-22T18:07:50Z 2018-08-22T18:07:50Z 2013-06 2018-08-21T18:17:15Z Article http://purl.org/eprint/type/ConferencePaper 9780784412992 http://hdl.handle.net/1721.1/117479 Brochard, Laurent et al. “Fracture Mechanisms in Organic-Rich Shales: Role of Kerogen.” Poromechanics V (June 2013): 2471-2480 © 2013 American Society of Civil Engineers. https://orcid.org/0000-0002-7089-8069 https://orcid.org/0000-0001-5559-4190 http://dx.doi.org/10.1061/9780784412992.288 Poromechanics V Creative Commons Attribution-Noncommercial-Share Alike http://creativecommons.org/licenses/by-nc-sa/4.0/ application/pdf American Society of Civil Engineers (ASCE) Other repository
spellingShingle Brochard, Laurent
Hantal, Gyorgy Miklos
Laubie, Hadrien H
Ulm, Franz-Josef
Pellenq, Roland Jm
Fracture Mechanisms in Organic-Rich Shales: Role of Kerogen
title Fracture Mechanisms in Organic-Rich Shales: Role of Kerogen
title_full Fracture Mechanisms in Organic-Rich Shales: Role of Kerogen
title_fullStr Fracture Mechanisms in Organic-Rich Shales: Role of Kerogen
title_full_unstemmed Fracture Mechanisms in Organic-Rich Shales: Role of Kerogen
title_short Fracture Mechanisms in Organic-Rich Shales: Role of Kerogen
title_sort fracture mechanisms in organic rich shales role of kerogen
url http://hdl.handle.net/1721.1/117479
https://orcid.org/0000-0002-7089-8069
https://orcid.org/0000-0001-5559-4190
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