Natural variability in eastern tropical Pacific nitrous oxide emissions

Thesis: S.B., Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences, 2018.

Bibliographic Details
Main Author: Boles, Elisabeth L
Other Authors: Andrew Babbin.
Format: Thesis
Language:eng
Published: Massachusetts Institute of Technology 2018
Subjects:
Online Access:http://hdl.handle.net/1721.1/118132
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author Boles, Elisabeth L
author2 Andrew Babbin.
author_facet Andrew Babbin.
Boles, Elisabeth L
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description Thesis: S.B., Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences, 2018.
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spelling mit-1721.1/1181322019-04-10T22:48:03Z Natural variability in eastern tropical Pacific nitrous oxide emissions Boles, Elisabeth L Andrew Babbin. Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences. Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences. Earth, Atmospheric, and Planetary Sciences. Thesis: S.B., Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences, 2018. Cataloged from PDF version of thesis. Includes bibliographical references (pages 45-47). Nitrous oxide (N2O) is a powerful greenhouse gas and ozone depleting substance, but its natural sources remain poorly constrained. Marine emissions are likely much higher than IPCC estimates predict, due to unusually high emissions from the oxygen minimum zones (OMZs) in the eastern tropical Pacific and Arabian Sea that are not accounted for in assessments. Measurements of atmospheric concentrations from a selection of AGAGE stations around the Pacific Ocean were combined with back-trajectories calculated using the HYSPLIT4 atmospheric model, in order to study the relative importance of OMZs on Pacific N2O emissions. Spatial and temporal variability in nitrous oxide concentrations were analyzed in order to determine potential regions of higher emissions, as well as the impacts of ENSO on biogeochemistry in the OMZs. Air parcels that passed over the oxygen minimum zone in the Eastern Tropical South Pacific were found to have N2O concentrations as much as 0.5 ppb higher than average. Average concentrations over the OMZ were modulated by an additional ~0.2 ppb higher during La Niia events and ~0.2 ppb lower during El Niio periods, a deviation of the same order of magnitude as N2O's seasonal cycle. Comparisons with CFC-12 and SF6 suggested strong influences on nitrous oxide concentrations in the Southern Hemisphere from stratosphere-troposphere exchange, but little influence from inter-hemispheric transport. by Elisabeth L. Boles. S.B. 2018-09-18T15:43:35Z 2018-09-18T15:43:35Z 2018 2018 Thesis http://hdl.handle.net/1721.1/118132 1051221754 eng MIT theses are protected by copyright. They may be viewed, downloaded, or printed from this source but further reproduction or distribution in any format is prohibited without written permission. http://dspace.mit.edu/handle/1721.1/7582 47 pages application/pdf p------ Massachusetts Institute of Technology
spellingShingle Earth, Atmospheric, and Planetary Sciences.
Boles, Elisabeth L
Natural variability in eastern tropical Pacific nitrous oxide emissions
title Natural variability in eastern tropical Pacific nitrous oxide emissions
title_full Natural variability in eastern tropical Pacific nitrous oxide emissions
title_fullStr Natural variability in eastern tropical Pacific nitrous oxide emissions
title_full_unstemmed Natural variability in eastern tropical Pacific nitrous oxide emissions
title_short Natural variability in eastern tropical Pacific nitrous oxide emissions
title_sort natural variability in eastern tropical pacific nitrous oxide emissions
topic Earth, Atmospheric, and Planetary Sciences.
url http://hdl.handle.net/1721.1/118132
work_keys_str_mv AT boleselisabethl naturalvariabilityineasterntropicalpacificnitrousoxideemissions