Porous Organic Polymers via Ring Opening Metathesis Polymerization

Highly porous and solution processable organic polymers that can be structurally tailored for various applications are in great demand. Previously reported strategies to prepare porous polymers usually rely on a high level of cross-linking or structurally rigid polymer backbones. We now demonstrate...

Full description

Bibliographic Details
Main Authors: Zhao, Yanchuan, He, Yuan, Swager, Timothy M
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Published: American Chemical Society (ACS) 2019
Online Access:https://hdl.handle.net/1721.1/121277
_version_ 1811090839090233344
author Zhao, Yanchuan
He, Yuan
Swager, Timothy M
author2 Massachusetts Institute of Technology. Department of Chemistry
author_facet Massachusetts Institute of Technology. Department of Chemistry
Zhao, Yanchuan
He, Yuan
Swager, Timothy M
author_sort Zhao, Yanchuan
collection MIT
description Highly porous and solution processable organic polymers that can be structurally tailored for various applications are in great demand. Previously reported strategies to prepare porous polymers usually rely on a high level of cross-linking or structurally rigid polymer backbones. We now demonstrate that one-dimensional linear polymers with flexible backbones prepared through ring opening metathesis polymerization can be highly porous. This new strategy allows facile access to diversified porous organic polymers having tunable mechanical/chemical properties bearing different functionalities.
first_indexed 2024-09-23T14:52:46Z
format Article
id mit-1721.1/121277
institution Massachusetts Institute of Technology
last_indexed 2024-09-23T14:52:46Z
publishDate 2019
publisher American Chemical Society (ACS)
record_format dspace
spelling mit-1721.1/1212772022-10-01T23:07:44Z Porous Organic Polymers via Ring Opening Metathesis Polymerization Zhao, Yanchuan He, Yuan Swager, Timothy M Massachusetts Institute of Technology. Department of Chemistry Highly porous and solution processable organic polymers that can be structurally tailored for various applications are in great demand. Previously reported strategies to prepare porous polymers usually rely on a high level of cross-linking or structurally rigid polymer backbones. We now demonstrate that one-dimensional linear polymers with flexible backbones prepared through ring opening metathesis polymerization can be highly porous. This new strategy allows facile access to diversified porous organic polymers having tunable mechanical/chemical properties bearing different functionalities. National Science Foundation (U.S.) (Award DMR-1410718) 2019-06-14T15:14:05Z 2019-06-14T15:14:05Z 2018-03 2018-01 2019-03-25T15:51:53Z Article http://purl.org/eprint/type/JournalArticle 2161-1653 2161-1653 https://hdl.handle.net/1721.1/121277 Zhao, Yanchuan et al. “Porous Organic Polymers via Ring Opening Metathesis Polymerization.” ACS Macro Letters 7, 3 (February 2018): 300–304 © 2018 American Chemical Society http://dx.doi.org/10.1021/ACSMACROLETT.8B00041 ACS Macro Letters Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) Prof. Swager
spellingShingle Zhao, Yanchuan
He, Yuan
Swager, Timothy M
Porous Organic Polymers via Ring Opening Metathesis Polymerization
title Porous Organic Polymers via Ring Opening Metathesis Polymerization
title_full Porous Organic Polymers via Ring Opening Metathesis Polymerization
title_fullStr Porous Organic Polymers via Ring Opening Metathesis Polymerization
title_full_unstemmed Porous Organic Polymers via Ring Opening Metathesis Polymerization
title_short Porous Organic Polymers via Ring Opening Metathesis Polymerization
title_sort porous organic polymers via ring opening metathesis polymerization
url https://hdl.handle.net/1721.1/121277
work_keys_str_mv AT zhaoyanchuan porousorganicpolymersviaringopeningmetathesispolymerization
AT heyuan porousorganicpolymersviaringopeningmetathesispolymerization
AT swagertimothym porousorganicpolymersviaringopeningmetathesispolymerization