Porous Organic Polymers via Ring Opening Metathesis Polymerization
Highly porous and solution processable organic polymers that can be structurally tailored for various applications are in great demand. Previously reported strategies to prepare porous polymers usually rely on a high level of cross-linking or structurally rigid polymer backbones. We now demonstrate...
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American Chemical Society (ACS)
2019
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Online Access: | https://hdl.handle.net/1721.1/121277 |
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author | Zhao, Yanchuan He, Yuan Swager, Timothy M |
author2 | Massachusetts Institute of Technology. Department of Chemistry |
author_facet | Massachusetts Institute of Technology. Department of Chemistry Zhao, Yanchuan He, Yuan Swager, Timothy M |
author_sort | Zhao, Yanchuan |
collection | MIT |
description | Highly porous and solution processable organic polymers that can be structurally tailored for various applications are in great demand. Previously reported strategies to prepare porous polymers usually rely on a high level of cross-linking or structurally rigid polymer backbones. We now demonstrate that one-dimensional linear polymers with flexible backbones prepared through ring opening metathesis polymerization can be highly porous. This new strategy allows facile access to diversified porous organic polymers having tunable mechanical/chemical properties bearing different functionalities. |
first_indexed | 2024-09-23T14:52:46Z |
format | Article |
id | mit-1721.1/121277 |
institution | Massachusetts Institute of Technology |
last_indexed | 2024-09-23T14:52:46Z |
publishDate | 2019 |
publisher | American Chemical Society (ACS) |
record_format | dspace |
spelling | mit-1721.1/1212772022-10-01T23:07:44Z Porous Organic Polymers via Ring Opening Metathesis Polymerization Zhao, Yanchuan He, Yuan Swager, Timothy M Massachusetts Institute of Technology. Department of Chemistry Highly porous and solution processable organic polymers that can be structurally tailored for various applications are in great demand. Previously reported strategies to prepare porous polymers usually rely on a high level of cross-linking or structurally rigid polymer backbones. We now demonstrate that one-dimensional linear polymers with flexible backbones prepared through ring opening metathesis polymerization can be highly porous. This new strategy allows facile access to diversified porous organic polymers having tunable mechanical/chemical properties bearing different functionalities. National Science Foundation (U.S.) (Award DMR-1410718) 2019-06-14T15:14:05Z 2019-06-14T15:14:05Z 2018-03 2018-01 2019-03-25T15:51:53Z Article http://purl.org/eprint/type/JournalArticle 2161-1653 2161-1653 https://hdl.handle.net/1721.1/121277 Zhao, Yanchuan et al. “Porous Organic Polymers via Ring Opening Metathesis Polymerization.” ACS Macro Letters 7, 3 (February 2018): 300–304 © 2018 American Chemical Society http://dx.doi.org/10.1021/ACSMACROLETT.8B00041 ACS Macro Letters Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Chemical Society (ACS) Prof. Swager |
spellingShingle | Zhao, Yanchuan He, Yuan Swager, Timothy M Porous Organic Polymers via Ring Opening Metathesis Polymerization |
title | Porous Organic Polymers via Ring Opening Metathesis Polymerization |
title_full | Porous Organic Polymers via Ring Opening Metathesis Polymerization |
title_fullStr | Porous Organic Polymers via Ring Opening Metathesis Polymerization |
title_full_unstemmed | Porous Organic Polymers via Ring Opening Metathesis Polymerization |
title_short | Porous Organic Polymers via Ring Opening Metathesis Polymerization |
title_sort | porous organic polymers via ring opening metathesis polymerization |
url | https://hdl.handle.net/1721.1/121277 |
work_keys_str_mv | AT zhaoyanchuan porousorganicpolymersviaringopeningmetathesispolymerization AT heyuan porousorganicpolymersviaringopeningmetathesispolymerization AT swagertimothym porousorganicpolymersviaringopeningmetathesispolymerization |