Poly(para-arylene)s via [2+2+2]
We report a versatile new synthetic route to poly(para-phenylene)s (PPPs) and related poly(para-arylene)s containing high degrees of substitution not readily available by other methods. Our method transforms highly soluble, alkyne-containing polymers into PPPs via high-yielding, transition metal-med...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Article |
| Language: | en_US |
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American Chemical Society
2019
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| Online Access: | https://hdl.handle.net/1721.1/121411 |
| _version_ | 1811079581755506688 |
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| author | Swager, Timothy M Batson, Joel Marcus |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Swager, Timothy M Batson, Joel Marcus |
| author_sort | Swager, Timothy M |
| collection | MIT |
| description | We report a versatile new synthetic route to poly(para-phenylene)s (PPPs) and related poly(para-arylene)s containing high degrees of substitution not readily available by other methods. Our method transforms highly soluble, alkyne-containing polymers into PPPs via high-yielding, transition metal-mediated [2+2+2] cyclizations. |
| first_indexed | 2024-09-23T11:17:17Z |
| format | Article |
| id | mit-1721.1/121411 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T11:17:17Z |
| publishDate | 2019 |
| publisher | American Chemical Society |
| record_format | dspace |
| spelling | mit-1721.1/1214112022-10-01T02:36:58Z Poly(para-arylene)s via [2+2+2] Swager, Timothy M Batson, Joel Marcus Massachusetts Institute of Technology. Department of Chemistry Swager, Timothy M. We report a versatile new synthetic route to poly(para-phenylene)s (PPPs) and related poly(para-arylene)s containing high degrees of substitution not readily available by other methods. Our method transforms highly soluble, alkyne-containing polymers into PPPs via high-yielding, transition metal-mediated [2+2+2] cyclizations. National Science Foundation (U.S.) (Grant DMR-1005810) 2019-06-25T16:59:45Z 2019-06-25T16:59:45Z 2012-08-27 Article http://purl.org/eprint/type/JournalArticle 2161-1653 https://hdl.handle.net/1721.1/121411 Batson, Joel M., and Timothy M. Swager. “Poly( Para-Arylene)s via [2+2+2].” ACS Macro Letters, 1, 9 (September 2012): 1121–23. en_US http://dx.doi.org/10.1021/mz300352m ACS Macro Letters Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf application/msword American Chemical Society Prof. Swager via Erja Kajosalo |
| spellingShingle | Swager, Timothy M Batson, Joel Marcus Poly(para-arylene)s via [2+2+2] |
| title | Poly(para-arylene)s via [2+2+2] |
| title_full | Poly(para-arylene)s via [2+2+2] |
| title_fullStr | Poly(para-arylene)s via [2+2+2] |
| title_full_unstemmed | Poly(para-arylene)s via [2+2+2] |
| title_short | Poly(para-arylene)s via [2+2+2] |
| title_sort | poly para arylene s via 2 2 2 |
| url | https://hdl.handle.net/1721.1/121411 |
| work_keys_str_mv | AT swagertimothym polyparaarylenesvia222 AT batsonjoelmarcus polyparaarylenesvia222 |