Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes
Catalytic phosphiranation has been achieved, allowing preparation of trans-1-R-2-phenylphosphiranes (R = t-Bu: 1-t-Bu; i-Pr: 1-i-Pr) from the corresponding dibenzo-7-(R)-7-phospha-norbornadiene (RPA, A = C₁₄H₁₀, anthracene) and styrene in 73% and 57% isolated yields, respectively. The cocatalyst sys...
| Main Authors: | , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS)
2019
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| Online Access: | https://hdl.handle.net/1721.1/122286 |