Epidermal biopolysaccharides from plant seeds enable biodegradable turbulent drag reduction

The high cost of synthetic polymers has been a key impediment limiting the widespread adoption of polymer drag reduction techniques in large-scale engineering applications, such as marine drag reduction. To address consumable cost constraints, we investigate the use of high molar mass biopolysacchar...

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Main Authors: Rajappan, Anoop, McKinley, Gareth H
Other Authors: Massachusetts Institute of Technology. Department of Mechanical Engineering
Format: Article
Published: Springer Science and Business Media LLC 2020
Online Access:https://hdl.handle.net/1721.1/123544
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author Rajappan, Anoop
McKinley, Gareth H
author2 Massachusetts Institute of Technology. Department of Mechanical Engineering
author_facet Massachusetts Institute of Technology. Department of Mechanical Engineering
Rajappan, Anoop
McKinley, Gareth H
author_sort Rajappan, Anoop
collection MIT
description The high cost of synthetic polymers has been a key impediment limiting the widespread adoption of polymer drag reduction techniques in large-scale engineering applications, such as marine drag reduction. To address consumable cost constraints, we investigate the use of high molar mass biopolysaccharides, present in the mucilaginous epidermis of plant seeds, as inexpensive drag reducers in large Reynolds number turbulent flows. Specifically, we study the aqueous mucilage extracted from flax seeds (Linum usitatissimum) and compare its drag reduction efficacy to that of poly(ethylene oxide) or PEO, a common synthetic polymer widely used as a drag reducing agent in aqueous flows. Macromolecular and rheological characterisation confirm the presence of high molar mass (U+2265 2 MDa) polysaccharides in the extracted mucilage, with an acidic fraction comprising negatively charged chains. Frictional drag measurements, performed inside a bespoke Taylor-Couette apparatus, show that the as-extracted mucilage has comparable drag reduction performance under turbulent flow conditions as aqueous PEO solutions, while concurrently offering advantages in terms of raw material cost, availability, and bio-compatibility. Our results indicate that plant-sourced mucilage can potentially serve as a cost-effective and eco-friendly substitute for synthetic drag reducing polymers in large scale turbulent flow applications. Keywords: fluid dynamics; mechanical engineering; polymers; rheology
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spelling mit-1721.1/1235442022-09-29T19:25:48Z Epidermal biopolysaccharides from plant seeds enable biodegradable turbulent drag reduction Rajappan, Anoop McKinley, Gareth H Massachusetts Institute of Technology. Department of Mechanical Engineering The high cost of synthetic polymers has been a key impediment limiting the widespread adoption of polymer drag reduction techniques in large-scale engineering applications, such as marine drag reduction. To address consumable cost constraints, we investigate the use of high molar mass biopolysaccharides, present in the mucilaginous epidermis of plant seeds, as inexpensive drag reducers in large Reynolds number turbulent flows. Specifically, we study the aqueous mucilage extracted from flax seeds (Linum usitatissimum) and compare its drag reduction efficacy to that of poly(ethylene oxide) or PEO, a common synthetic polymer widely used as a drag reducing agent in aqueous flows. Macromolecular and rheological characterisation confirm the presence of high molar mass (U+2265 2 MDa) polysaccharides in the extracted mucilage, with an acidic fraction comprising negatively charged chains. Frictional drag measurements, performed inside a bespoke Taylor-Couette apparatus, show that the as-extracted mucilage has comparable drag reduction performance under turbulent flow conditions as aqueous PEO solutions, while concurrently offering advantages in terms of raw material cost, availability, and bio-compatibility. Our results indicate that plant-sourced mucilage can potentially serve as a cost-effective and eco-friendly substitute for synthetic drag reducing polymers in large scale turbulent flow applications. Keywords: fluid dynamics; mechanical engineering; polymers; rheology National Science Foundation (U.S.). Materials Research Science and Engineering Centers (Program) (Award DMR-1419807) 2020-01-22T21:33:50Z 2020-01-22T21:33:50Z 2019-12 2019-08 Article http://purl.org/eprint/type/JournalArticle 2045-2322 https://hdl.handle.net/1721.1/123544 Rajappan, Anoop, and Gareth H. McKinley. "Epidermal biopolysaccharides from plant seeds enable biodegradable turbulent drag reduction." Scientific Reports 9, 1 (December 2019): 18263 © The Author(s) 2019 http://dx.doi.org/10.1038/s41598-019-54521-3 Scientific Reports Creative Commons Attribution 4.0 International license https://creativecommons.org/licenses/by/4.0/ application/pdf Springer Science and Business Media LLC Scientific Reports
spellingShingle Rajappan, Anoop
McKinley, Gareth H
Epidermal biopolysaccharides from plant seeds enable biodegradable turbulent drag reduction
title Epidermal biopolysaccharides from plant seeds enable biodegradable turbulent drag reduction
title_full Epidermal biopolysaccharides from plant seeds enable biodegradable turbulent drag reduction
title_fullStr Epidermal biopolysaccharides from plant seeds enable biodegradable turbulent drag reduction
title_full_unstemmed Epidermal biopolysaccharides from plant seeds enable biodegradable turbulent drag reduction
title_short Epidermal biopolysaccharides from plant seeds enable biodegradable turbulent drag reduction
title_sort epidermal biopolysaccharides from plant seeds enable biodegradable turbulent drag reduction
url https://hdl.handle.net/1721.1/123544
work_keys_str_mv AT rajappananoop epidermalbiopolysaccharidesfromplantseedsenablebiodegradableturbulentdragreduction
AT mckinleygarethh epidermalbiopolysaccharidesfromplantseedsenablebiodegradableturbulentdragreduction