Granular shape memory ceramic packings

Although bulk shape memory ceramics (SMCs) are brittle, in particulate form they exhibit large recoverable strains in both shape memory and superelastic modes. Here, we investigate the fundamentals of mechanically- and thermally-triggered martensitic transformation of granular SMC packings. Specific...

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Main Authors: Yu, Hang, Hassani Gangaraj, Seyyed Mostafa, Du, Zehui, Gan, Chee Lip, Schuh, Christopher A
Other Authors: Massachusetts Institute of Technology. Department of Materials Science and Engineering
Format: Article
Language:en_US
Published: Elsevier BV 2020
Online Access:https://hdl.handle.net/1721.1/123686
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author Yu, Hang
Hassani Gangaraj, Seyyed Mostafa
Du, Zehui
Gan, Chee Lip
Schuh, Christopher A
author2 Massachusetts Institute of Technology. Department of Materials Science and Engineering
author_facet Massachusetts Institute of Technology. Department of Materials Science and Engineering
Yu, Hang
Hassani Gangaraj, Seyyed Mostafa
Du, Zehui
Gan, Chee Lip
Schuh, Christopher A
author_sort Yu, Hang
collection MIT
description Although bulk shape memory ceramics (SMCs) are brittle, in particulate form they exhibit large recoverable strains in both shape memory and superelastic modes. Here, we investigate the fundamentals of mechanically- and thermally-triggered martensitic transformation of granular SMC packings. Specifically, (ZrO2)1-x-(CeO2)x is studied in three different composition regimes. In the shape memory regime (below the martensite finish temperature), confined uniaxial compression leads to martensite re-orientation in the granular SMC packing, with the peak intensity of preferred crystallographic orientation increasing with external loading. In the intermediate regime (between austenite start and martensite start temperatures), confined uniaxial compression leads to irreversible martensitic transformation with the transformed volume increasing with external loading. This provides direct evidence of stress-induced martensitic transformation in granular SMCs. In the superelastic regime (above the austenite finish temperature), confined uniaxial compression leads to forward (during loading) and reverse (during unloading) martensitic transformation, manifesting in a large hysteresis loop in each load-unload cycle with remarkably high energy dissipation density. Based on finite element modeling of SMC particles in contact, we explore the martensitic transformation under non-uniform Hertzian stresses, which in turn provides insight on the experimental results. Keywords: Shape memory; Granular materials; Zirconia; Martensitic transformation; Superelasticity
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spelling mit-1721.1/1236862022-09-28T11:28:58Z Granular shape memory ceramic packings Yu, Hang Hassani Gangaraj, Seyyed Mostafa Du, Zehui Gan, Chee Lip Schuh, Christopher A Massachusetts Institute of Technology. Department of Materials Science and Engineering Schuh, Christopher A. Although bulk shape memory ceramics (SMCs) are brittle, in particulate form they exhibit large recoverable strains in both shape memory and superelastic modes. Here, we investigate the fundamentals of mechanically- and thermally-triggered martensitic transformation of granular SMC packings. Specifically, (ZrO2)1-x-(CeO2)x is studied in three different composition regimes. In the shape memory regime (below the martensite finish temperature), confined uniaxial compression leads to martensite re-orientation in the granular SMC packing, with the peak intensity of preferred crystallographic orientation increasing with external loading. In the intermediate regime (between austenite start and martensite start temperatures), confined uniaxial compression leads to irreversible martensitic transformation with the transformed volume increasing with external loading. This provides direct evidence of stress-induced martensitic transformation in granular SMCs. In the superelastic regime (above the austenite finish temperature), confined uniaxial compression leads to forward (during loading) and reverse (during unloading) martensitic transformation, manifesting in a large hysteresis loop in each load-unload cycle with remarkably high energy dissipation density. Based on finite element modeling of SMC particles in contact, we explore the martensitic transformation under non-uniform Hertzian stresses, which in turn provides insight on the experimental results. Keywords: Shape memory; Granular materials; Zirconia; Martensitic transformation; Superelasticity 2020-01-27T20:40:22Z 2020-01-27T20:40:22Z 2017-06 2016-12 Article http://purl.org/eprint/type/JournalArticle 1359-6454 https://hdl.handle.net/1721.1/123686 Yu, Hang Z. et al. "Granular shape memory ceramic packings." Acta Materialia 132 (June 2017): 455-466 © 2017 Acta Materialia Inc en_US http://dx.doi.org/10.1016/j.actamat.2017.04.057 Acta Materialia Creative Commons Attribution-NonCommercial-NoDerivs License http://creativecommons.org/licenses/by-nc-nd/4.0/ application/msword application/pdf Elsevier BV Prof. Schuh via Erja Kajosalo
spellingShingle Yu, Hang
Hassani Gangaraj, Seyyed Mostafa
Du, Zehui
Gan, Chee Lip
Schuh, Christopher A
Granular shape memory ceramic packings
title Granular shape memory ceramic packings
title_full Granular shape memory ceramic packings
title_fullStr Granular shape memory ceramic packings
title_full_unstemmed Granular shape memory ceramic packings
title_short Granular shape memory ceramic packings
title_sort granular shape memory ceramic packings
url https://hdl.handle.net/1721.1/123686
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AT hassanigangarajseyyedmostafa granularshapememoryceramicpackings
AT duzehui granularshapememoryceramicpackings
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AT schuhchristophera granularshapememoryceramicpackings