Increase in global emissions of HFC-23 despite near-total expected reductions

Under the Kigali Amendment to the Montreal Protocol, new controls are being implemented to reduce emissions of HFC-23 (CHF3), a by-product during the manufacture of HCFC-22 (CHClF2). Starting in 2015, China and India, who dominate global HCFC-22 production (75% in 2017), set out ambitious programs t...

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Main Author: Prinn, Ronald G.
Other Authors: Massachusetts Institute of Technology. Center for Global Change Science
Format: Article
Language:English
Published: Springer Science and Business Media LLC 2020
Online Access:https://hdl.handle.net/1721.1/124686
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author Prinn, Ronald G.
author2 Massachusetts Institute of Technology. Center for Global Change Science
author_facet Massachusetts Institute of Technology. Center for Global Change Science
Prinn, Ronald G.
author_sort Prinn, Ronald G.
collection MIT
description Under the Kigali Amendment to the Montreal Protocol, new controls are being implemented to reduce emissions of HFC-23 (CHF3), a by-product during the manufacture of HCFC-22 (CHClF2). Starting in 2015, China and India, who dominate global HCFC-22 production (75% in 2017), set out ambitious programs to reduce HFC-23 emissions. Here, we estimate that these measures should have seen global emissions drop by 87% between 2014 and 2017. Instead, atmospheric observations show that emissions have increased and in 2018 were higher than at any point in history (15.9 ±0.9Ggyr−1). Given the magnitude of the discrepancy between expected and observation-inferred emissions, it is likely that the reported reductions have not fully materialized or there may be substantial unreported production of HCFC-22, resulting in unaccounted-for HFC-23 by-product emissions. The difference between reported and observation-inferred estimates suggests that an additional ~309 Tg CO 2-equivalent emissions were added to the atmosphere between 2015 and 2017. ©2020
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spelling mit-1721.1/1246862022-09-27T17:13:10Z Increase in global emissions of HFC-23 despite near-total expected reductions Prinn, Ronald G. Massachusetts Institute of Technology. Center for Global Change Science Under the Kigali Amendment to the Montreal Protocol, new controls are being implemented to reduce emissions of HFC-23 (CHF3), a by-product during the manufacture of HCFC-22 (CHClF2). Starting in 2015, China and India, who dominate global HCFC-22 production (75% in 2017), set out ambitious programs to reduce HFC-23 emissions. Here, we estimate that these measures should have seen global emissions drop by 87% between 2014 and 2017. Instead, atmospheric observations show that emissions have increased and in 2018 were higher than at any point in history (15.9 ±0.9Ggyr−1). Given the magnitude of the discrepancy between expected and observation-inferred emissions, it is likely that the reported reductions have not fully materialized or there may be substantial unreported production of HCFC-22, resulting in unaccounted-for HFC-23 by-product emissions. The difference between reported and observation-inferred estimates suggests that an additional ~309 Tg CO 2-equivalent emissions were added to the atmosphere between 2015 and 2017. ©2020 2020-04-16T14:02:27Z 2020-04-16T14:02:27Z 2020-01 2020-04-07T12:10:32Z Article http://purl.org/eprint/type/JournalArticle 2041-1723 https://hdl.handle.net/1721.1/124686 Stanley, K.M., et al., "Increase in global emissions of HFC-23 despite near-total expected reductions." Nature communications 11, 1 (January 2020): no. 397 doi 10.1038/s41467-019-13899-4 ©2020 Author(s) en 10.1038/s41467-019-13899-4 Nature communications Creative Commons Attribution 4.0 International license https://creativecommons.org/licenses/by/4.0/ application/pdf Springer Science and Business Media LLC Nature
spellingShingle Prinn, Ronald G.
Increase in global emissions of HFC-23 despite near-total expected reductions
title Increase in global emissions of HFC-23 despite near-total expected reductions
title_full Increase in global emissions of HFC-23 despite near-total expected reductions
title_fullStr Increase in global emissions of HFC-23 despite near-total expected reductions
title_full_unstemmed Increase in global emissions of HFC-23 despite near-total expected reductions
title_short Increase in global emissions of HFC-23 despite near-total expected reductions
title_sort increase in global emissions of hfc 23 despite near total expected reductions
url https://hdl.handle.net/1721.1/124686
work_keys_str_mv AT prinnronaldg increaseinglobalemissionsofhfc23despiteneartotalexpectedreductions