Intercomparison measurements of two 33 S-enriched sulfur isotope standards
Despite widespread applications of sulfur isotope mass-independent fractionation (MIF) signals for probing terrestrial and extra-terrestrial environments, there has been no international sulfur isotope reference material available for normalization of Δ33S and Δ36S data. International reference mate...
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| Format: | Article |
| Language: | English |
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Royal Society of Chemistry (RSC)
2020
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| Online Access: | https://hdl.handle.net/1721.1/124850 |
| _version_ | 1826191606115467264 |
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| author | Ono, Shuhei |
| author2 | Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences |
| author_facet | Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences Ono, Shuhei |
| author_sort | Ono, Shuhei |
| collection | MIT |
| description | Despite widespread applications of sulfur isotope mass-independent fractionation (MIF) signals for probing terrestrial and extra-terrestrial environments, there has been no international sulfur isotope reference material available for normalization of Δ33S and Δ36S data. International reference materials to anchor isotope values are useful for interlaboratory data comparisons and are needed to evaluate, e.g., whether issues exist associated with blanks and mass spectrometry when using different analytical approaches. We synthesized two sodium sulfate samples enriched in 33S with different magnitudes, and termed them S-MIF-1 and S-MIF-2, respectively. The sulfur isotopic compositions of these two samples were measured in five different laboratories using two distinct techniques to place them on the V-CDT scale for δ34S and a provisional V-CDT scale for Δ33S and Δ36S. We obtained average δ34S values of S-MIF-1 = 10.26 ± 0.22‰ and S-MIF-2 = 21.53 ± 0.26‰ (1σ, versus V-CDT). The average Δ33S and Δ36S values of S-MIF-1 were determined to be 9.54 ± 0.09‰ and -0.11 ± 0.25‰, respectively, while the average Δ33S and Δ36S values of S-MIF-2 are 11.39 ± 0.08‰ and -0.33 ± 0.13‰ (1σ, versus V-CDT). The lack of variation among the interlaboratory isotopic values suggests sufficient homogeneity of S-MIF-1 and S-MIF-2, especially for Δ33S. Although additional measurements may be needed to ensure the accuracy of the isotopic compositions of S-MIF-1 and S-MIF-2, they can serve as working standards for routine Δ33S analysis to improve data consistency, and have the potential to serve as secondary sulfur isotope reference materials to address issues such as scale contraction/expansion and for normalization and reporting of Δ33S and Δ36S between laboratories. For the same reasons as listed for sulfur isotopes, the same standards were also artificially enriched in 17O. The calibration is still in progress but first estimations gave Δ17O = 3.3 ± 0.3‰ with unassigned δ18O. ©2019 |
| first_indexed | 2024-09-23T08:58:31Z |
| format | Article |
| id | mit-1721.1/124850 |
| institution | Massachusetts Institute of Technology |
| language | English |
| last_indexed | 2024-09-23T08:58:31Z |
| publishDate | 2020 |
| publisher | Royal Society of Chemistry (RSC) |
| record_format | dspace |
| spelling | mit-1721.1/1248502022-09-30T12:33:47Z Intercomparison measurements of two 33 S-enriched sulfur isotope standards Ono, Shuhei Massachusetts Institute of Technology. Department of Earth, Atmospheric, and Planetary Sciences Despite widespread applications of sulfur isotope mass-independent fractionation (MIF) signals for probing terrestrial and extra-terrestrial environments, there has been no international sulfur isotope reference material available for normalization of Δ33S and Δ36S data. International reference materials to anchor isotope values are useful for interlaboratory data comparisons and are needed to evaluate, e.g., whether issues exist associated with blanks and mass spectrometry when using different analytical approaches. We synthesized two sodium sulfate samples enriched in 33S with different magnitudes, and termed them S-MIF-1 and S-MIF-2, respectively. The sulfur isotopic compositions of these two samples were measured in five different laboratories using two distinct techniques to place them on the V-CDT scale for δ34S and a provisional V-CDT scale for Δ33S and Δ36S. We obtained average δ34S values of S-MIF-1 = 10.26 ± 0.22‰ and S-MIF-2 = 21.53 ± 0.26‰ (1σ, versus V-CDT). The average Δ33S and Δ36S values of S-MIF-1 were determined to be 9.54 ± 0.09‰ and -0.11 ± 0.25‰, respectively, while the average Δ33S and Δ36S values of S-MIF-2 are 11.39 ± 0.08‰ and -0.33 ± 0.13‰ (1σ, versus V-CDT). The lack of variation among the interlaboratory isotopic values suggests sufficient homogeneity of S-MIF-1 and S-MIF-2, especially for Δ33S. Although additional measurements may be needed to ensure the accuracy of the isotopic compositions of S-MIF-1 and S-MIF-2, they can serve as working standards for routine Δ33S analysis to improve data consistency, and have the potential to serve as secondary sulfur isotope reference materials to address issues such as scale contraction/expansion and for normalization and reporting of Δ33S and Δ36S between laboratories. For the same reasons as listed for sulfur isotopes, the same standards were also artificially enriched in 17O. The calibration is still in progress but first estimations gave Δ17O = 3.3 ± 0.3‰ with unassigned δ18O. ©2019 2020-04-24T15:10:14Z 2020-04-24T15:10:14Z 2019-03 2019-01 2020-04-06T19:38:11Z Article http://purl.org/eprint/type/JournalArticle 0267-9477 1364-5544 https://hdl.handle.net/1721.1/124850 Gen, L., et al., "Intercomparison measurements of two 33 S-enriched sulfur isotope standards." Journal of analytical atomic spectrometry 34, 6 (Mar. 2019): no. 1263 doi 10.1039/C8JA00451J ©2019 Author(s) en 10.1039/C8JA00451J Journal of analytical atomic spectrometry Creative Commons Attribution 3.0 unported license https://creativecommons.org/licenses/by/3.0/ application/pdf Royal Society of Chemistry (RSC) Royal Society of Chemistry (RSC) |
| spellingShingle | Ono, Shuhei Intercomparison measurements of two 33 S-enriched sulfur isotope standards |
| title | Intercomparison measurements of two 33 S-enriched sulfur isotope standards |
| title_full | Intercomparison measurements of two 33 S-enriched sulfur isotope standards |
| title_fullStr | Intercomparison measurements of two 33 S-enriched sulfur isotope standards |
| title_full_unstemmed | Intercomparison measurements of two 33 S-enriched sulfur isotope standards |
| title_short | Intercomparison measurements of two 33 S-enriched sulfur isotope standards |
| title_sort | intercomparison measurements of two 33 s enriched sulfur isotope standards |
| url | https://hdl.handle.net/1721.1/124850 |
| work_keys_str_mv | AT onoshuhei intercomparisonmeasurementsoftwo33senrichedsulfurisotopestandards |