A unified relationship for evaporation kinetics at low Mach numbers

We experimentally realized and elucidated kinetically limited evaporation where the molecular gas dynamics close to the liquid–vapour interface dominates the overall transport. This process fundamentally dictates the performance of various evaporative systems and has received significant theoretical...

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Main Authors: Lu, Zhengmao, Wilke, Kyle L., Vaartstra, Geoffrey, Wang, Evelyn N.
Other Authors: Massachusetts Institute of Technology. Department of Mechanical Engineering
Format: Article
Language:English
Published: Springer Science and Business Media LLC 2020
Online Access:https://hdl.handle.net/1721.1/125179
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author Lu, Zhengmao
Wilke, Kyle L.
Vaartstra, Geoffrey
Wang, Evelyn N.
author2 Massachusetts Institute of Technology. Department of Mechanical Engineering
author_facet Massachusetts Institute of Technology. Department of Mechanical Engineering
Lu, Zhengmao
Wilke, Kyle L.
Vaartstra, Geoffrey
Wang, Evelyn N.
author_sort Lu, Zhengmao
collection MIT
description We experimentally realized and elucidated kinetically limited evaporation where the molecular gas dynamics close to the liquid–vapour interface dominates the overall transport. This process fundamentally dictates the performance of various evaporative systems and has received significant theoretical interest. However, experimental studies have been limited due to the difficulty of isolating the interfacial thermal resistance. Here, we overcome this challenge using an ultrathin nanoporous membrane in a pure vapour ambient. We demonstrate a fundamental relationship between the evaporation flux and driving potential in a dimensionless form, which unifies kinetically limited evaporation under different working conditions. We model the nonequilibrium gas kinetics and show good agreement between experiments and theory. Our work provides a general figure of merit for evaporative heat transfer as well as design guidelines for achieving efficient evaporation in applications such as water purification, steam generation, and thermal management.
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spelling mit-1721.1/1251792022-10-01T00:26:41Z A unified relationship for evaporation kinetics at low Mach numbers Lu, Zhengmao Wilke, Kyle L. Vaartstra, Geoffrey Wang, Evelyn N. Massachusetts Institute of Technology. Department of Mechanical Engineering We experimentally realized and elucidated kinetically limited evaporation where the molecular gas dynamics close to the liquid–vapour interface dominates the overall transport. This process fundamentally dictates the performance of various evaporative systems and has received significant theoretical interest. However, experimental studies have been limited due to the difficulty of isolating the interfacial thermal resistance. Here, we overcome this challenge using an ultrathin nanoporous membrane in a pure vapour ambient. We demonstrate a fundamental relationship between the evaporation flux and driving potential in a dimensionless form, which unifies kinetically limited evaporation under different working conditions. We model the nonequilibrium gas kinetics and show good agreement between experiments and theory. Our work provides a general figure of merit for evaporative heat transfer as well as design guidelines for achieving efficient evaporation in applications such as water purification, steam generation, and thermal management. National Science Foundation (U.S.) (Award ECS-0335765) 2020-05-12T15:17:25Z 2020-05-12T15:17:25Z 2019-05 2020-01-23T13:57:45Z Article http://purl.org/eprint/type/JournalArticle 2041-1723 https://hdl.handle.net/1721.1/125179 Lu, Zhengmao et al. “A unified relationship for evaporation kinetics at low Mach numbers.” Nature Communications 10 (2019): 2368 © 2019 The Author(s) en 10.1038/S41467-019-10209-W Nature Communications Creative Commons Attribution 4.0 International license https://creativecommons.org/licenses/by/4.0/ application/pdf Springer Science and Business Media LLC Nature
spellingShingle Lu, Zhengmao
Wilke, Kyle L.
Vaartstra, Geoffrey
Wang, Evelyn N.
A unified relationship for evaporation kinetics at low Mach numbers
title A unified relationship for evaporation kinetics at low Mach numbers
title_full A unified relationship for evaporation kinetics at low Mach numbers
title_fullStr A unified relationship for evaporation kinetics at low Mach numbers
title_full_unstemmed A unified relationship for evaporation kinetics at low Mach numbers
title_short A unified relationship for evaporation kinetics at low Mach numbers
title_sort unified relationship for evaporation kinetics at low mach numbers
url https://hdl.handle.net/1721.1/125179
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