Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole
A modular and facile route has been developed to synthesize functionalized 2,5-di(thiophen-2-yl)-1-H-arylpyrroles from readily available starting materials. These units are compatible with various polymerization conditions and are versatile building blocks for conjugated polymers. The polymers show...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
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Wiley
2020
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| Online Access: | https://hdl.handle.net/1721.1/125533 |
| _version_ | 1811081854872190976 |
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| author | Truong, Tran N. B Savagatrup, Suchol Jeon, Intak Swager, Timothy M |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Truong, Tran N. B Savagatrup, Suchol Jeon, Intak Swager, Timothy M |
| author_sort | Truong, Tran N. B |
| collection | MIT |
| description | A modular and facile route has been developed to synthesize functionalized 2,5-di(thiophen-2-yl)-1-H-arylpyrroles from readily available starting materials. These units are compatible with various polymerization conditions and are versatile building blocks for conjugated polymers. The polymers show high thermal stability and solubility in a number of solvents. Characterization of the polymers reveals a correlation between molecular packing, controllable by polymer design, and charge carrier mobility. |
| first_indexed | 2024-09-23T11:53:32Z |
| format | Article |
| id | mit-1721.1/125533 |
| institution | Massachusetts Institute of Technology |
| language | English |
| last_indexed | 2024-09-23T11:53:32Z |
| publishDate | 2020 |
| publisher | Wiley |
| record_format | dspace |
| spelling | mit-1721.1/1255332022-09-27T22:37:58Z Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole Truong, Tran N. B Savagatrup, Suchol Jeon, Intak Swager, Timothy M Massachusetts Institute of Technology. Department of Chemistry Massachusetts Institute of Technology. Department of Materials Science and Engineering A modular and facile route has been developed to synthesize functionalized 2,5-di(thiophen-2-yl)-1-H-arylpyrroles from readily available starting materials. These units are compatible with various polymerization conditions and are versatile building blocks for conjugated polymers. The polymers show high thermal stability and solubility in a number of solvents. Characterization of the polymers reveals a correlation between molecular packing, controllable by polymer design, and charge carrier mobility. 2020-05-28T12:25:59Z 2020-05-28T12:25:59Z 2018-06 2020-01-10T18:03:22Z Article http://purl.org/eprint/type/JournalArticle 1099-0518 0887-624X https://hdl.handle.net/1721.1/125533 Truong, Tran N. B. et al. “Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole.” Journal of polymer science. Part A, Polymer chemistry 56 (2018): 1133-1139 © 2018 The Author(s) en https://dx.doi.org/10.1002/POLA.28990 Journal of polymer science. Part A, Polymer chemistry Creative Commons Attribution-Noncommercial-Share Alike http://creativecommons.org/licenses/by-nc-sa/4.0/ application/pdf Wiley PMC |
| spellingShingle | Truong, Tran N. B Savagatrup, Suchol Jeon, Intak Swager, Timothy M Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole |
| title | Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole |
| title_full | Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole |
| title_fullStr | Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole |
| title_full_unstemmed | Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole |
| title_short | Modular synthesis of polymers containing 2,5-di(thiophenyl)- N-arylpyrrole |
| title_sort | modular synthesis of polymers containing 2 5 di thiophenyl n arylpyrrole |
| url | https://hdl.handle.net/1721.1/125533 |
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