Nontrigonal constraint enhances 1,2-addition reactivity of phosphazenes

The syntheses and 1,2-addition reactivities of nontrigonal phosphazenes supported by trianionic tricoordinating chelates of the type L3PNdipp (3: L3 = N[CHC(tBu)O]23-; 4: L3 = N(o-NMeC6H4)23-; dipp = 2,6-diisopropylphenyl) are reported. These compounds are characterized by multinuclear NMR and singl...

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Bibliographic Details
Main Authors: Lin, Yi-Chun, Gilhula, James C., Radosevich, Alexander T.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: Royal Society of Chemistry (RSC) 2020
Online Access:https://hdl.handle.net/1721.1/125725