Enantioselective synthesis of (-)-vallesine: late-stage C17-oxidation via complex indole boronation
The first enantioselective total synthesis of (-)-vallesine via a strategy that features a late-stage regioselective C17-oxidation followed by a highly stereoselective transannular cyclization is reported. The versatility of this approach is highlighted by the divergent synthesis of the archetypal a...
| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS)
2020
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| Subjects: | |
| Online Access: | https://hdl.handle.net/1721.1/125882 |