Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks

Triphenylene ligands hexasubstituted with amino or phenol groups afford two phases of electrically conductive layered two-dimensional metal-organic frameworks upon reaction with various metals. Regardless of the identity of the metal or chelating atom, π-stacking within the MOF layers is essential t...

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Main Authors: Miner, Elise Marie, Wang, Lu, Dinca, Mircea
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: Royal Society of Chemistry (RSC) 2020
Online Access:https://hdl.handle.net/1721.1/126095
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author Miner, Elise Marie
Wang, Lu
Dinca, Mircea
author2 Massachusetts Institute of Technology. Department of Chemistry
author_facet Massachusetts Institute of Technology. Department of Chemistry
Miner, Elise Marie
Wang, Lu
Dinca, Mircea
author_sort Miner, Elise Marie
collection MIT
description Triphenylene ligands hexasubstituted with amino or phenol groups afford two phases of electrically conductive layered two-dimensional metal-organic frameworks upon reaction with various metals. Regardless of the identity of the metal or chelating atom, π-stacking within the MOF layers is essential to achieve high electrical conductivity, redox activity, and catalytic activity.
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spelling mit-1721.1/1260952022-09-29T19:40:07Z Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks Modular O[subscript 2] electroreduction activity in triphenylene-based metal-organic frameworks Miner, Elise Marie Wang, Lu Dinca, Mircea Massachusetts Institute of Technology. Department of Chemistry Triphenylene ligands hexasubstituted with amino or phenol groups afford two phases of electrically conductive layered two-dimensional metal-organic frameworks upon reaction with various metals. Regardless of the identity of the metal or chelating atom, π-stacking within the MOF layers is essential to achieve high electrical conductivity, redox activity, and catalytic activity. MIT Energy Initiative Seed Fund (grant no. 015728-00168) 2020-07-08T19:34:31Z 2020-07-08T19:34:31Z 2018-06 2018-05 2019-12-16T19:39:56Z Article http://purl.org/eprint/type/JournalArticle 2041-6539 https://hdl.handle.net/1721.1/126095 Miner, Elise M., Lu Wang, and Mircea Dinca. "Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks." Chemical Science 2018, 9 (June 2018): no. 6286 doi 10.1039/C8SC02049C ©2018 Author(s) en 10.1039/C8SC02049C Chemical Science Creative Commons Attribution Noncommercial 3.0 unported license https://creativecommons.org/licenses/by-nc/3.0/ application/pdf Royal Society of Chemistry (RSC) Royal Society of Chemistry (RSC)
spellingShingle Miner, Elise Marie
Wang, Lu
Dinca, Mircea
Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks
title Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks
title_full Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks
title_fullStr Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks
title_full_unstemmed Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks
title_short Modular O2 electroreduction activity in triphenylene-based metal-organic frameworks
title_sort modular o2 electroreduction activity in triphenylene based metal organic frameworks
url https://hdl.handle.net/1721.1/126095
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AT minerelisemarie modularosubscript2electroreductionactivityintriphenylenebasedmetalorganicframeworks
AT wanglu modularosubscript2electroreductionactivityintriphenylenebasedmetalorganicframeworks
AT dincamircea modularosubscript2electroreductionactivityintriphenylenebasedmetalorganicframeworks