Voltage control of electrical, optical and magnetic properties of materials by solid state ionic transport and electrochemical reactions

Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, May, 2020

Bibliographic Details
Main Author: Huang, Mantao.
Other Authors: Geoffrey S. D. Beach.
Format: Thesis
Language:eng
Published: Massachusetts Institute of Technology 2020
Subjects:
Online Access:https://hdl.handle.net/1721.1/127898
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author Huang, Mantao.
author2 Geoffrey S. D. Beach.
author_facet Geoffrey S. D. Beach.
Huang, Mantao.
author_sort Huang, Mantao.
collection MIT
description Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, May, 2020
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spelling mit-1721.1/1278982020-10-09T03:01:44Z Voltage control of electrical, optical and magnetic properties of materials by solid state ionic transport and electrochemical reactions Huang, Mantao. Geoffrey S. D. Beach. Massachusetts Institute of Technology. Department of Materials Science and Engineering. Massachusetts Institute of Technology. Department of Materials Science and Engineering Materials Science and Engineering. Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, May, 2020 Cataloged from the official PDF of thesis. Includes bibliographical references (pages 139-153). Reversible post-fabrication control of material properties enables devices that can adapt to different needs or environmental conditions, and brings additional levels of functionality, paving the way towards applications such as reconfigurable electronics, reconfigurable antennas, active optical devices and energy efficient data storage. One promising way of achieving the controllability is through solid-state ionic transport and electrochemical reactions in thin film structures, where the properties of materials can be electrically controlled by a gate voltage in an addressable way. Here we explore using such ionic gating method to control the electrical, optical and magnetic properties of solid-state thin film layers, and show that large modification can be achieved for a wide range of properties. We demonstrate a new type of three terminal resistive switching device where the resistivity of a thin film conductive channel can be controlled by a gate voltage. We demonstrate solid-state ionic gating of the optical properties of metals and oxides and show the versatility of the approach by implementing voltage-controlled transmission, thin film interference, and switchable plasmonic colors. We also show that the approach allows for voltage control of ferrimagnetic order, demonstrating voltage induced 180-degree switching of the Néel vector, as a new way of magnetic bit writing. These findings extend the scope of voltage programmable materials and provide insights into the mechanisms of voltage controlled material properties by solid-state ionic transport and electrochemical reactions. by Mantao Huang. Ph. D. Ph.D. Massachusetts Institute of Technology, Department of Materials Science and Engineering 2020-10-08T21:29:23Z 2020-10-08T21:29:23Z 2020 2020 Thesis https://hdl.handle.net/1721.1/127898 1197626748 eng MIT theses may be protected by copyright. Please reuse MIT thesis content according to the MIT Libraries Permissions Policy, which is available through the URL provided. http://dspace.mit.edu/handle/1721.1/7582 153 pages application/pdf Massachusetts Institute of Technology
spellingShingle Materials Science and Engineering.
Huang, Mantao.
Voltage control of electrical, optical and magnetic properties of materials by solid state ionic transport and electrochemical reactions
title Voltage control of electrical, optical and magnetic properties of materials by solid state ionic transport and electrochemical reactions
title_full Voltage control of electrical, optical and magnetic properties of materials by solid state ionic transport and electrochemical reactions
title_fullStr Voltage control of electrical, optical and magnetic properties of materials by solid state ionic transport and electrochemical reactions
title_full_unstemmed Voltage control of electrical, optical and magnetic properties of materials by solid state ionic transport and electrochemical reactions
title_short Voltage control of electrical, optical and magnetic properties of materials by solid state ionic transport and electrochemical reactions
title_sort voltage control of electrical optical and magnetic properties of materials by solid state ionic transport and electrochemical reactions
topic Materials Science and Engineering.
url https://hdl.handle.net/1721.1/127898
work_keys_str_mv AT huangmantao voltagecontrolofelectricalopticalandmagneticpropertiesofmaterialsbysolidstateionictransportandelectrochemicalreactions