Triptycene-Based Ladder Polymers with One-Handed Helical Geometry
Here we report an efficient synthesis of optically active ladder-type molecules and polymers through intramolecular cyclization of chiral triptycenes containing bis[2-(4-alkoxyphenyl)ethynyl]phenylene units. The electrophile-induced cyclization reactions are directed away from the bridgehead carbon...
Main Authors: | Ikai, Tomoyuki, Yoshida, Takumu, Shinohara, Ken-ichi, Taniguchi, Tsuyoshi, Wada, Yuya, Swager, Timothy M |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS)
2020
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Online Access: | https://hdl.handle.net/1721.1/128144 |
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