Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal–Organic Frameworks

Triphenylene-Bridged Trinuclear Complexes of Cu: Models for Spin Interactions in Two-Dimensional Electrically Conductive Metal–Organic Frameworks

Reaction of 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) and 2,3,6,7,10,11-hexaaminotriphenylene (HATP) with [Cu(Me3tacn)]2+ (Me3tacn = 1,4,7-trimethyl-1,4,7-triazacyclononane) produces trigonal tricopper complexes [(Me3tacnCu)3(HOTP)]3+ (1) and [(Me3tacnCu)3(HITP)]4+ (2) (HOTP, HITP = hexaoxy- and...

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Bibliographic Details
Main Authors: Yang, Luming, He, Xin, Dinca, Mircea
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:English
Published: American Chemical Society (ACS) 2020
Online Access:https://hdl.handle.net/1721.1/128206

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