Interdigitated conducting tetrathiafulvalene-based coordination networks
Assembly of a novel ethylenedithio-tetrathiafulvalene (EDT-TTF) derivative bearing two adjacent 4-thiopyridyl groups with M(NCS)2 nodes (M = Fe, Co) leads to two isostructural 1D coordination polymers showing an enhancement of their electronic conductivity by six orders of magnitude (10[superscript...
| Main Authors: | , , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
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Royal Society of Chemistry (RSC)
2020
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| Online Access: | https://hdl.handle.net/1721.1/128208 |
| _version_ | 1811086522229719040 |
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| author | Bechu, Damien Xie, Lilia S. Le Breton, Nolwenn Choua, Sylvie Dinca, Mircea Hosseini, Mir Wais Baudron, Stéphane A. |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Bechu, Damien Xie, Lilia S. Le Breton, Nolwenn Choua, Sylvie Dinca, Mircea Hosseini, Mir Wais Baudron, Stéphane A. |
| author_sort | Bechu, Damien |
| collection | MIT |
| description | Assembly of a novel ethylenedithio-tetrathiafulvalene (EDT-TTF) derivative bearing two adjacent 4-thiopyridyl groups with M(NCS)2 nodes (M = Fe, Co) leads to two isostructural 1D coordination polymers showing an enhancement of their electronic conductivity by six orders of magnitude (10[superscript -6] vs. 10[superscript -12] S cm[superscript -1), upon surface oxidation by iodine and subsequent generation of EDT-TTF-based radicals. |
| first_indexed | 2024-09-23T13:27:16Z |
| format | Article |
| id | mit-1721.1/128208 |
| institution | Massachusetts Institute of Technology |
| language | English |
| last_indexed | 2024-09-23T13:27:16Z |
| publishDate | 2020 |
| publisher | Royal Society of Chemistry (RSC) |
| record_format | dspace |
| spelling | mit-1721.1/1282082022-09-28T14:21:41Z Interdigitated conducting tetrathiafulvalene-based coordination networks Bechu, Damien Xie, Lilia S. Le Breton, Nolwenn Choua, Sylvie Dinca, Mircea Hosseini, Mir Wais Baudron, Stéphane A. Massachusetts Institute of Technology. Department of Chemistry Assembly of a novel ethylenedithio-tetrathiafulvalene (EDT-TTF) derivative bearing two adjacent 4-thiopyridyl groups with M(NCS)2 nodes (M = Fe, Co) leads to two isostructural 1D coordination polymers showing an enhancement of their electronic conductivity by six orders of magnitude (10[superscript -6] vs. 10[superscript -12] S cm[superscript -1), upon surface oxidation by iodine and subsequent generation of EDT-TTF-based radicals. National Science Foundation (Award 1122374) 2020-10-26T20:24:43Z 2020-10-26T20:24:43Z 2020-01 2019-12 2020-10-21T15:07:21Z Article http://purl.org/eprint/type/JournalArticle 1359-7345 1364-548X https://hdl.handle.net/1721.1/128208 Bechu, Damien et al. "Interdigitated conducting tetrathiafulvalene-based coordination networks." Chemical Communications 56, 16 (January 2020): 2407-2410 © 2020 The Royal Society of Chemistry en http://dx.doi.org/10.1039/c9cc09960c Chemical Communications Creative Commons Attribution-Noncommercial-Share Alike http://creativecommons.org/licenses/by-nc-sa/4.0/ application/pdf Royal Society of Chemistry (RSC) Prof. Dinca via Ye Li |
| spellingShingle | Bechu, Damien Xie, Lilia S. Le Breton, Nolwenn Choua, Sylvie Dinca, Mircea Hosseini, Mir Wais Baudron, Stéphane A. Interdigitated conducting tetrathiafulvalene-based coordination networks |
| title | Interdigitated conducting tetrathiafulvalene-based coordination networks |
| title_full | Interdigitated conducting tetrathiafulvalene-based coordination networks |
| title_fullStr | Interdigitated conducting tetrathiafulvalene-based coordination networks |
| title_full_unstemmed | Interdigitated conducting tetrathiafulvalene-based coordination networks |
| title_short | Interdigitated conducting tetrathiafulvalene-based coordination networks |
| title_sort | interdigitated conducting tetrathiafulvalene based coordination networks |
| url | https://hdl.handle.net/1721.1/128208 |
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