Effect of annealing on magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy

Magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy (PMA) are investigated as a function of annealing temperature (T anneal ) and annealing time for several capping layers. Magnetic properties in films capped by TaO x vary markedly with T anneal ; the sa...

Full description

Bibliographic Details
Main Authors: Ueda, Kohei, Tan, Aik Jun, Beach, Geoffrey Stephen
Other Authors: Massachusetts Institute of Technology. Department of Materials Science and Engineering
Format: Article
Language:English
Published: AIP Publishing 2020
Online Access:https://hdl.handle.net/1721.1/128665
_version_ 1826190177729511424
author Ueda, Kohei
Tan, Aik Jun
Beach, Geoffrey Stephen
author2 Massachusetts Institute of Technology. Department of Materials Science and Engineering
author_facet Massachusetts Institute of Technology. Department of Materials Science and Engineering
Ueda, Kohei
Tan, Aik Jun
Beach, Geoffrey Stephen
author_sort Ueda, Kohei
collection MIT
description Magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy (PMA) are investigated as a function of annealing temperature (T anneal ) and annealing time for several capping layers. Magnetic properties in films capped by TaO x vary markedly with T anneal ; the saturation magnetization and coercivity vary progressively with increasing T anneal up to 300°C, and above that temperature, PMA is lost abruptly. By comparing the annealing temperature dependence for Co-dominated and Gd-dominated compositions close to the magnetization compensation point, the data are readily explained by preferential oxidation of Gd during annealing. When films are capped by a Ta/Pt bilayer, the film properties are stable up T anneal = 300 °C, indicating that oxidation at high temperatures is effectively blocked, but the abrupt loss of PMA for T anneal > 300 °C is still observed. X-ray diffraction measurement reveals that the amorphous structure of the films remains the same after high-temperature annealing that is sufficient to remove PMA, indicating that crystallization from the amorphous phase is not responsible for the lack of PMA. Instead, our results suggest that high annealing temperatures may cause segregation of Co and Gd atoms in the films, which reduces anisotropic pair-pair correlations responsible for the observed bulk PMA in the as-grown state. ©2018 Author(s).
first_indexed 2024-09-23T08:36:16Z
format Article
id mit-1721.1/128665
institution Massachusetts Institute of Technology
language English
last_indexed 2024-09-23T08:36:16Z
publishDate 2020
publisher AIP Publishing
record_format dspace
spelling mit-1721.1/1286652022-09-23T13:13:18Z Effect of annealing on magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy Ueda, Kohei Tan, Aik Jun Beach, Geoffrey Stephen Massachusetts Institute of Technology. Department of Materials Science and Engineering Magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy (PMA) are investigated as a function of annealing temperature (T anneal ) and annealing time for several capping layers. Magnetic properties in films capped by TaO x vary markedly with T anneal ; the saturation magnetization and coercivity vary progressively with increasing T anneal up to 300°C, and above that temperature, PMA is lost abruptly. By comparing the annealing temperature dependence for Co-dominated and Gd-dominated compositions close to the magnetization compensation point, the data are readily explained by preferential oxidation of Gd during annealing. When films are capped by a Ta/Pt bilayer, the film properties are stable up T anneal = 300 °C, indicating that oxidation at high temperatures is effectively blocked, but the abrupt loss of PMA for T anneal > 300 °C is still observed. X-ray diffraction measurement reveals that the amorphous structure of the films remains the same after high-temperature annealing that is sufficient to remove PMA, indicating that crystallization from the amorphous phase is not responsible for the lack of PMA. Instead, our results suggest that high annealing temperatures may cause segregation of Co and Gd atoms in the films, which reduces anisotropic pair-pair correlations responsible for the observed bulk PMA in the as-grown state. ©2018 Author(s). NSF (DMR-14-19807) NSF (NSF-ECCS-1408172) 2020-11-25T22:32:19Z 2020-11-25T22:32:19Z 2018-12 2018-08 2019-09-17T15:29:52Z Article http://purl.org/eprint/type/JournalArticle 2158-3226 https://hdl.handle.net/1721.1/128665 Ueda, Kohei et al., "Effect of annealing on magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy." AIP Advances 8, 12 (December 2018): 125204 ©2018 Authors en https://dx.doi.org/10.1063/1.5054164 AIP Advances Creative Commons Attribution 4.0 International license https://creativecommons.org/licenses/by/4.0/ application/pdf AIP Publishing American Institute of Physics (AIP)
spellingShingle Ueda, Kohei
Tan, Aik Jun
Beach, Geoffrey Stephen
Effect of annealing on magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy
title Effect of annealing on magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy
title_full Effect of annealing on magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy
title_fullStr Effect of annealing on magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy
title_full_unstemmed Effect of annealing on magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy
title_short Effect of annealing on magnetic properties in ferrimagnetic GdCo alloy films with bulk perpendicular magnetic anisotropy
title_sort effect of annealing on magnetic properties in ferrimagnetic gdco alloy films with bulk perpendicular magnetic anisotropy
url https://hdl.handle.net/1721.1/128665
work_keys_str_mv AT uedakohei effectofannealingonmagneticpropertiesinferrimagneticgdcoalloyfilmswithbulkperpendicularmagneticanisotropy
AT tanaikjun effectofannealingonmagneticpropertiesinferrimagneticgdcoalloyfilmswithbulkperpendicularmagneticanisotropy
AT beachgeoffreystephen effectofannealingonmagneticpropertiesinferrimagneticgdcoalloyfilmswithbulkperpendicularmagneticanisotropy