Broadband transparent optical phase change materials for high-performance nonvolatile photonics

Optical phase change materials (O-PCMs), a unique group of materials featuring exceptional optical property contrast upon a solid-state phase transition, have found widespread adoption in photonic applications such as switches, routers and reconfigurable meta-optics. Current O-PCMs, such as Ge–Sb–Te...

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Main Authors: Zhang, Yifei, Chou, Jeffrey B., Li, Junying, Li, Huashan, Du, Qingyang, Yadav, Anupama, Zhou, Si, Shalaginov, Mikhail, Fang, Zhuoran, Zhong, Huikai, Roberts, Christopher, Robinson, Paul, Bohlin, Bridget, Ríos, Carlos, Lin, Hongtao, Kang, Myungkoo, Gu, Tian, Warner, Jamie, Liberman, Vladimir, Richardson, Kathleen, Hu, Juejun
Other Authors: Massachusetts Institute of Technology. Materials Systems Laboratory
Format: Article
Language:English
Published: Springer Science and Business Media LLC 2021
Online Access:https://hdl.handle.net/1721.1/129736
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author Zhang, Yifei
Chou, Jeffrey B.
Li, Junying
Li, Huashan
Du, Qingyang
Yadav, Anupama
Zhou, Si
Shalaginov, Mikhail
Fang, Zhuoran
Zhong, Huikai
Roberts, Christopher
Robinson, Paul
Bohlin, Bridget
Ríos, Carlos
Lin, Hongtao
Kang, Myungkoo
Gu, Tian
Warner, Jamie
Liberman, Vladimir
Richardson, Kathleen
Hu, Juejun
author2 Massachusetts Institute of Technology. Materials Systems Laboratory
author_facet Massachusetts Institute of Technology. Materials Systems Laboratory
Zhang, Yifei
Chou, Jeffrey B.
Li, Junying
Li, Huashan
Du, Qingyang
Yadav, Anupama
Zhou, Si
Shalaginov, Mikhail
Fang, Zhuoran
Zhong, Huikai
Roberts, Christopher
Robinson, Paul
Bohlin, Bridget
Ríos, Carlos
Lin, Hongtao
Kang, Myungkoo
Gu, Tian
Warner, Jamie
Liberman, Vladimir
Richardson, Kathleen
Hu, Juejun
author_sort Zhang, Yifei
collection MIT
description Optical phase change materials (O-PCMs), a unique group of materials featuring exceptional optical property contrast upon a solid-state phase transition, have found widespread adoption in photonic applications such as switches, routers and reconfigurable meta-optics. Current O-PCMs, such as Ge–Sb–Te (GST), exhibit large contrast of both refractive index (Δn) and optical loss (Δk), simultaneously. The coupling of both optical properties fundamentally limits the performance of many applications. Here we introduce a new class of O-PCMs based on Ge–Sb–Se–Te (GSST) which breaks this traditional coupling. The optimized alloy, Ge₂Sb₂Se₄Te₁, combines broadband transparency (1–18.5 μm), large optical contrast (Δn = 2.0), and significantly improved glass forming ability, enabling an entirely new range of infrared and thermal photonic devices. We further demonstrate nonvolatile integrated optical switches with record low loss and large contrast ratio and an electrically-addressed spatial light modulator pixel, thereby validating its promise as a material for scalable nonvolatile photonics.
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spelling mit-1721.1/1297362022-09-29T13:13:52Z Broadband transparent optical phase change materials for high-performance nonvolatile photonics Zhang, Yifei Chou, Jeffrey B. Li, Junying Li, Huashan Du, Qingyang Yadav, Anupama Zhou, Si Shalaginov, Mikhail Fang, Zhuoran Zhong, Huikai Roberts, Christopher Robinson, Paul Bohlin, Bridget Ríos, Carlos Lin, Hongtao Kang, Myungkoo Gu, Tian Warner, Jamie Liberman, Vladimir Richardson, Kathleen Hu, Juejun Massachusetts Institute of Technology. Materials Systems Laboratory Massachusetts Institute of Technology. Microsystems Technology Laboratories Massachusetts Institute of Technology. Department of Materials Science and Engineering Lincoln Laboratory MIT Materials Research Laboratory Optical phase change materials (O-PCMs), a unique group of materials featuring exceptional optical property contrast upon a solid-state phase transition, have found widespread adoption in photonic applications such as switches, routers and reconfigurable meta-optics. Current O-PCMs, such as Ge–Sb–Te (GST), exhibit large contrast of both refractive index (Δn) and optical loss (Δk), simultaneously. The coupling of both optical properties fundamentally limits the performance of many applications. Here we introduce a new class of O-PCMs based on Ge–Sb–Se–Te (GSST) which breaks this traditional coupling. The optimized alloy, Ge₂Sb₂Se₄Te₁, combines broadband transparency (1–18.5 μm), large optical contrast (Δn = 2.0), and significantly improved glass forming ability, enabling an entirely new range of infrared and thermal photonic devices. We further demonstrate nonvolatile integrated optical switches with record low loss and large contrast ratio and an electrically-addressed spatial light modulator pixel, thereby validating its promise as a material for scalable nonvolatile photonics. 2021-02-10T16:46:23Z 2021-02-10T16:46:23Z 2019-09 2020-09-11T17:47:43Z Article http://purl.org/eprint/type/JournalArticle 2041-1723 https://hdl.handle.net/1721.1/129736 Zhang, Yifei et al. "Broadband transparent optical phase change materials for high-performance nonvolatile photonics." Nature Communications 10, 1 (September 2019) 4279 © 2019, The Author(s). en 10.1038/S41467-019-12196-4 Nature Communications Creative Commons Attribution 4.0 International license https://creativecommons.org/licenses/by/4.0/ application/pdf Springer Science and Business Media LLC Nature
spellingShingle Zhang, Yifei
Chou, Jeffrey B.
Li, Junying
Li, Huashan
Du, Qingyang
Yadav, Anupama
Zhou, Si
Shalaginov, Mikhail
Fang, Zhuoran
Zhong, Huikai
Roberts, Christopher
Robinson, Paul
Bohlin, Bridget
Ríos, Carlos
Lin, Hongtao
Kang, Myungkoo
Gu, Tian
Warner, Jamie
Liberman, Vladimir
Richardson, Kathleen
Hu, Juejun
Broadband transparent optical phase change materials for high-performance nonvolatile photonics
title Broadband transparent optical phase change materials for high-performance nonvolatile photonics
title_full Broadband transparent optical phase change materials for high-performance nonvolatile photonics
title_fullStr Broadband transparent optical phase change materials for high-performance nonvolatile photonics
title_full_unstemmed Broadband transparent optical phase change materials for high-performance nonvolatile photonics
title_short Broadband transparent optical phase change materials for high-performance nonvolatile photonics
title_sort broadband transparent optical phase change materials for high performance nonvolatile photonics
url https://hdl.handle.net/1721.1/129736
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