Broadband transparent optical phase change materials for high-performance nonvolatile photonics
Optical phase change materials (O-PCMs), a unique group of materials featuring exceptional optical property contrast upon a solid-state phase transition, have found widespread adoption in photonic applications such as switches, routers and reconfigurable meta-optics. Current O-PCMs, such as Ge–Sb–Te...
Main Authors: | , , , , , , , , , , , , , , , , , , , , |
---|---|
Other Authors: | |
Format: | Article |
Language: | English |
Published: |
Springer Science and Business Media LLC
2021
|
Online Access: | https://hdl.handle.net/1721.1/129736 |
_version_ | 1811091981418364928 |
---|---|
author | Zhang, Yifei Chou, Jeffrey B. Li, Junying Li, Huashan Du, Qingyang Yadav, Anupama Zhou, Si Shalaginov, Mikhail Fang, Zhuoran Zhong, Huikai Roberts, Christopher Robinson, Paul Bohlin, Bridget Ríos, Carlos Lin, Hongtao Kang, Myungkoo Gu, Tian Warner, Jamie Liberman, Vladimir Richardson, Kathleen Hu, Juejun |
author2 | Massachusetts Institute of Technology. Materials Systems Laboratory |
author_facet | Massachusetts Institute of Technology. Materials Systems Laboratory Zhang, Yifei Chou, Jeffrey B. Li, Junying Li, Huashan Du, Qingyang Yadav, Anupama Zhou, Si Shalaginov, Mikhail Fang, Zhuoran Zhong, Huikai Roberts, Christopher Robinson, Paul Bohlin, Bridget Ríos, Carlos Lin, Hongtao Kang, Myungkoo Gu, Tian Warner, Jamie Liberman, Vladimir Richardson, Kathleen Hu, Juejun |
author_sort | Zhang, Yifei |
collection | MIT |
description | Optical phase change materials (O-PCMs), a unique group of materials featuring exceptional optical property contrast upon a solid-state phase transition, have found widespread adoption in photonic applications such as switches, routers and reconfigurable meta-optics. Current O-PCMs, such as Ge–Sb–Te (GST), exhibit large contrast of both refractive index (Δn) and optical loss (Δk), simultaneously. The coupling of both optical properties fundamentally limits the performance of many applications. Here we introduce a new class of O-PCMs based on Ge–Sb–Se–Te (GSST) which breaks this traditional coupling. The optimized alloy, Ge₂Sb₂Se₄Te₁, combines broadband transparency (1–18.5 μm), large optical contrast (Δn = 2.0), and significantly improved glass forming ability, enabling an entirely new range of infrared and thermal photonic devices. We further demonstrate nonvolatile integrated optical switches with record low loss and large contrast ratio and an electrically-addressed spatial light modulator pixel, thereby validating its promise as a material for scalable nonvolatile photonics. |
first_indexed | 2024-09-23T15:11:01Z |
format | Article |
id | mit-1721.1/129736 |
institution | Massachusetts Institute of Technology |
language | English |
last_indexed | 2024-09-23T15:11:01Z |
publishDate | 2021 |
publisher | Springer Science and Business Media LLC |
record_format | dspace |
spelling | mit-1721.1/1297362022-09-29T13:13:52Z Broadband transparent optical phase change materials for high-performance nonvolatile photonics Zhang, Yifei Chou, Jeffrey B. Li, Junying Li, Huashan Du, Qingyang Yadav, Anupama Zhou, Si Shalaginov, Mikhail Fang, Zhuoran Zhong, Huikai Roberts, Christopher Robinson, Paul Bohlin, Bridget Ríos, Carlos Lin, Hongtao Kang, Myungkoo Gu, Tian Warner, Jamie Liberman, Vladimir Richardson, Kathleen Hu, Juejun Massachusetts Institute of Technology. Materials Systems Laboratory Massachusetts Institute of Technology. Microsystems Technology Laboratories Massachusetts Institute of Technology. Department of Materials Science and Engineering Lincoln Laboratory MIT Materials Research Laboratory Optical phase change materials (O-PCMs), a unique group of materials featuring exceptional optical property contrast upon a solid-state phase transition, have found widespread adoption in photonic applications such as switches, routers and reconfigurable meta-optics. Current O-PCMs, such as Ge–Sb–Te (GST), exhibit large contrast of both refractive index (Δn) and optical loss (Δk), simultaneously. The coupling of both optical properties fundamentally limits the performance of many applications. Here we introduce a new class of O-PCMs based on Ge–Sb–Se–Te (GSST) which breaks this traditional coupling. The optimized alloy, Ge₂Sb₂Se₄Te₁, combines broadband transparency (1–18.5 μm), large optical contrast (Δn = 2.0), and significantly improved glass forming ability, enabling an entirely new range of infrared and thermal photonic devices. We further demonstrate nonvolatile integrated optical switches with record low loss and large contrast ratio and an electrically-addressed spatial light modulator pixel, thereby validating its promise as a material for scalable nonvolatile photonics. 2021-02-10T16:46:23Z 2021-02-10T16:46:23Z 2019-09 2020-09-11T17:47:43Z Article http://purl.org/eprint/type/JournalArticle 2041-1723 https://hdl.handle.net/1721.1/129736 Zhang, Yifei et al. "Broadband transparent optical phase change materials for high-performance nonvolatile photonics." Nature Communications 10, 1 (September 2019) 4279 © 2019, The Author(s). en 10.1038/S41467-019-12196-4 Nature Communications Creative Commons Attribution 4.0 International license https://creativecommons.org/licenses/by/4.0/ application/pdf Springer Science and Business Media LLC Nature |
spellingShingle | Zhang, Yifei Chou, Jeffrey B. Li, Junying Li, Huashan Du, Qingyang Yadav, Anupama Zhou, Si Shalaginov, Mikhail Fang, Zhuoran Zhong, Huikai Roberts, Christopher Robinson, Paul Bohlin, Bridget Ríos, Carlos Lin, Hongtao Kang, Myungkoo Gu, Tian Warner, Jamie Liberman, Vladimir Richardson, Kathleen Hu, Juejun Broadband transparent optical phase change materials for high-performance nonvolatile photonics |
title | Broadband transparent optical phase change materials for high-performance nonvolatile photonics |
title_full | Broadband transparent optical phase change materials for high-performance nonvolatile photonics |
title_fullStr | Broadband transparent optical phase change materials for high-performance nonvolatile photonics |
title_full_unstemmed | Broadband transparent optical phase change materials for high-performance nonvolatile photonics |
title_short | Broadband transparent optical phase change materials for high-performance nonvolatile photonics |
title_sort | broadband transparent optical phase change materials for high performance nonvolatile photonics |
url | https://hdl.handle.net/1721.1/129736 |
work_keys_str_mv | AT zhangyifei broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT choujeffreyb broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT lijunying broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT lihuashan broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT duqingyang broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT yadavanupama broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT zhousi broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT shalaginovmikhail broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT fangzhuoran broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT zhonghuikai broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT robertschristopher broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT robinsonpaul broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT bohlinbridget broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT rioscarlos broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT linhongtao broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT kangmyungkoo broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT gutian broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT warnerjamie broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT libermanvladimir broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT richardsonkathleen broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics AT hujuejun broadbandtransparentopticalphasechangematerialsforhighperformancenonvolatilephotonics |