Gradient-morph LiCoO2 single crystals with stabilized energy density above 3400 W h L−1
The cycling stability of LiCoO[subscript 2] under high voltages (>4.5 V) was plagued by hybrid anion- and cation-redox (HACR) induced oxygen escape and uncontrolled phase collapse. With DEMS and in situ XANES mapping at the NSLS-II, we demonstrate that oxygen escape triggers irreversible transfor...
Main Authors: | Zhu, Zhi, Yu, Daiwei, Shi, Zhe, Gao, Rui, Xiao, Xianghui, Waluyo, Iradwikanari, Ge, Mingyuan, Dong, Yanhao, Xue, Weijiang, Xu, Guiyin, Lee, Wah-Keat, Hunt, Adrian, Li, Ju |
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Other Authors: | Massachusetts Institute of Technology. Department of Nuclear Science and Engineering |
Format: | Article |
Published: |
Royal Society of Chemistry (RSC)
2021
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Online Access: | https://hdl.handle.net/1721.1/132623 |
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