Fabrication and Supercapacitor Applications of Multiwall Carbon Nanotube Thin Films

Multiwalled carbon nanotubes (MWCNTs) are a one-dimensional nanomaterial with several desirable material properties, including high mechanical tensile modulus and strength, high electrical conductivity, and good thermal conductivity. A wide variety of techniques have been optimized to synthesize MWC...

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Main Authors: Jiang, Kyle, Gerhardt, Rosario A.
Other Authors: Massachusetts Institute of Technology. Department of Mechanical Engineering
Format: Article
Published: Multidisciplinary Digital Publishing Institute 2021
Online Access:https://hdl.handle.net/1721.1/133179
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author Jiang, Kyle
Gerhardt, Rosario A.
author2 Massachusetts Institute of Technology. Department of Mechanical Engineering
author_facet Massachusetts Institute of Technology. Department of Mechanical Engineering
Jiang, Kyle
Gerhardt, Rosario A.
author_sort Jiang, Kyle
collection MIT
description Multiwalled carbon nanotubes (MWCNTs) are a one-dimensional nanomaterial with several desirable material properties, including high mechanical tensile modulus and strength, high electrical conductivity, and good thermal conductivity. A wide variety of techniques have been optimized to synthesize MWCNTs and to fabricate thin films of MWCNTs. These synthesis and fabrication methods vary based on precursor materials, process parameters, and physical and chemical principals, and have a strong influence on the properties of the nanotubes and films. Thus, the fabrication methods determine the performance of devices that can exploit the advantageous material properties of MWCNTs. Techniques for the fabrication of carbon nanotubes and carbon nanotube thin films are reviewed, followed by a discussion of the use of MWCNTs as an electrode material for electrochemical double-layer supercapacitors (EDLCs). EDLCs feature high power density, excellent reversibility and lifetime, and improved energy density over electrolytic capacitors. Beyond surveying fabrication techniques previously explored for MWCNT electrodes, an alternative approach based on inkjet printing capable of depositing a small amount of active material is discussed. Such an approach allows for a high degree of control over electrode properties and can potentially reduce cost and active material waste, which are essential components to the gradual conversion to green energy.
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spelling mit-1721.1/1331792023-07-07T20:52:39Z Fabrication and Supercapacitor Applications of Multiwall Carbon Nanotube Thin Films Jiang, Kyle Gerhardt, Rosario A. Massachusetts Institute of Technology. Department of Mechanical Engineering Multiwalled carbon nanotubes (MWCNTs) are a one-dimensional nanomaterial with several desirable material properties, including high mechanical tensile modulus and strength, high electrical conductivity, and good thermal conductivity. A wide variety of techniques have been optimized to synthesize MWCNTs and to fabricate thin films of MWCNTs. These synthesis and fabrication methods vary based on precursor materials, process parameters, and physical and chemical principals, and have a strong influence on the properties of the nanotubes and films. Thus, the fabrication methods determine the performance of devices that can exploit the advantageous material properties of MWCNTs. Techniques for the fabrication of carbon nanotubes and carbon nanotube thin films are reviewed, followed by a discussion of the use of MWCNTs as an electrode material for electrochemical double-layer supercapacitors (EDLCs). EDLCs feature high power density, excellent reversibility and lifetime, and improved energy density over electrolytic capacitors. Beyond surveying fabrication techniques previously explored for MWCNT electrodes, an alternative approach based on inkjet printing capable of depositing a small amount of active material is discussed. Such an approach allows for a high degree of control over electrode properties and can potentially reduce cost and active material waste, which are essential components to the gradual conversion to green energy. 2021-10-27T17:33:34Z 2021-10-27T17:33:34Z 2021-09-30 2021-10-12T14:18:02Z Article http://purl.org/eprint/type/JournalArticle https://hdl.handle.net/1721.1/133179 C 7 (4): 70 (2021) PUBLISHER_CC http://dx.doi.org/10.3390/c7040070 Creative Commons Attribution https://creativecommons.org/licenses/by/4.0/ application/pdf Multidisciplinary Digital Publishing Institute Multidisciplinary Digital Publishing Institute
spellingShingle Jiang, Kyle
Gerhardt, Rosario A.
Fabrication and Supercapacitor Applications of Multiwall Carbon Nanotube Thin Films
title Fabrication and Supercapacitor Applications of Multiwall Carbon Nanotube Thin Films
title_full Fabrication and Supercapacitor Applications of Multiwall Carbon Nanotube Thin Films
title_fullStr Fabrication and Supercapacitor Applications of Multiwall Carbon Nanotube Thin Films
title_full_unstemmed Fabrication and Supercapacitor Applications of Multiwall Carbon Nanotube Thin Films
title_short Fabrication and Supercapacitor Applications of Multiwall Carbon Nanotube Thin Films
title_sort fabrication and supercapacitor applications of multiwall carbon nanotube thin films
url https://hdl.handle.net/1721.1/133179
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AT gerhardtrosarioa fabricationandsupercapacitorapplicationsofmultiwallcarbonnanotubethinfilms