On the origin & thermal stability of Arrokoth's and Pluto's ices

© 2020 In this paper we discuss in a thermodynamic, geologically empirical way the long-term nature of the stable majority ices that could be present in Kuiper Belt object (KBO) 2014 MU69 (also called Arrokoth; hereafter “MU69”) after its 4.6 Gyr residence in the Edgeworth-Kuiper belt (EKB) as a col...

Full description

Bibliographic Details
Format: Article
Language:English
Published: Elsevier BV 2021
Online Access:https://hdl.handle.net/1721.1/133768
_version_ 1826208740014030848
collection MIT
description © 2020 In this paper we discuss in a thermodynamic, geologically empirical way the long-term nature of the stable majority ices that could be present in Kuiper Belt object (KBO) 2014 MU69 (also called Arrokoth; hereafter “MU69”) after its 4.6 Gyr residence in the Edgeworth-Kuiper belt (EKB) as a cold classical object. We compare the upper bounds for the gas production rate (~1024 molecules/s) measured by the New Horizons (NH) spacecraft flyby on 01 Jan 2019 to estimates for the outgassing flux rates from a suite of common cometary and KBO ices at the average ~ 40 K sunlit surface temperature of MU69, but do not find the upper limit very constraining except for the most volatile of species (e.g. CO, N2, CH4). More constraining is the stability versus sublimation into vacuum requirement over Myr to Gyr, and from this we find only 3 common ices that are truly refractory: HCN, CH3OH, and H2O (in order of increasing stability), while NH3 and H2CO ices are marginally stable and may be removed by any positive temperature excursions in the EKB, as produced every 108–109 years by nearby supernovae and passing O/B stars. To date the NH team has reported the presence of abundant CH3OH and H2O on MU69's surface (Stern et al., 2019; Grundy et al., 2020). NH3 has been searched for, but not found. We predict that future absorption feature detections, if any are ever derived from higher signal-to-noise ratio spectra, will be due to an HCN or poly-H2CO based species. Consideration of the conditions present in the EKB region during the formation era of MU69 lead us to state that it is highly likely that it “formed in the dark”, in an optically thick mid-plane, unable to see the nascent, variable, highly luminous Young Stellar Object (YSO)/TTauri Sun, and that KBOs contain HCN and CH3OH ice phases in addition to the H2O ice phases found in their short period (SP) comet descendants. Finally, when we apply our ice thermal stability analysis to bodies/populations related to MU69, we find that methanol ice is likely ubiquitous in the outer solar system; that if Pluto isn't a fully differentiated body, then it must have gained its hypervolatile ices from proto-planetary disk (PPD) sources in the first few Myr of the solar system's existence; and that hypervolatile rich, highly primordial comet C/2016 R2 was placed onto an Oort Cloud orbit on a similar few Myr timescale.
first_indexed 2024-09-23T14:10:45Z
format Article
id mit-1721.1/133768
institution Massachusetts Institute of Technology
language English
last_indexed 2024-09-23T14:10:45Z
publishDate 2021
publisher Elsevier BV
record_format dspace
spelling mit-1721.1/1337682022-04-01T17:27:48Z On the origin & thermal stability of Arrokoth's and Pluto's ices © 2020 In this paper we discuss in a thermodynamic, geologically empirical way the long-term nature of the stable majority ices that could be present in Kuiper Belt object (KBO) 2014 MU69 (also called Arrokoth; hereafter “MU69”) after its 4.6 Gyr residence in the Edgeworth-Kuiper belt (EKB) as a cold classical object. We compare the upper bounds for the gas production rate (~1024 molecules/s) measured by the New Horizons (NH) spacecraft flyby on 01 Jan 2019 to estimates for the outgassing flux rates from a suite of common cometary and KBO ices at the average ~ 40 K sunlit surface temperature of MU69, but do not find the upper limit very constraining except for the most volatile of species (e.g. CO, N2, CH4). More constraining is the stability versus sublimation into vacuum requirement over Myr to Gyr, and from this we find only 3 common ices that are truly refractory: HCN, CH3OH, and H2O (in order of increasing stability), while NH3 and H2CO ices are marginally stable and may be removed by any positive temperature excursions in the EKB, as produced every 108–109 years by nearby supernovae and passing O/B stars. To date the NH team has reported the presence of abundant CH3OH and H2O on MU69's surface (Stern et al., 2019; Grundy et al., 2020). NH3 has been searched for, but not found. We predict that future absorption feature detections, if any are ever derived from higher signal-to-noise ratio spectra, will be due to an HCN or poly-H2CO based species. Consideration of the conditions present in the EKB region during the formation era of MU69 lead us to state that it is highly likely that it “formed in the dark”, in an optically thick mid-plane, unable to see the nascent, variable, highly luminous Young Stellar Object (YSO)/TTauri Sun, and that KBOs contain HCN and CH3OH ice phases in addition to the H2O ice phases found in their short period (SP) comet descendants. Finally, when we apply our ice thermal stability analysis to bodies/populations related to MU69, we find that methanol ice is likely ubiquitous in the outer solar system; that if Pluto isn't a fully differentiated body, then it must have gained its hypervolatile ices from proto-planetary disk (PPD) sources in the first few Myr of the solar system's existence; and that hypervolatile rich, highly primordial comet C/2016 R2 was placed onto an Oort Cloud orbit on a similar few Myr timescale. 2021-10-27T19:56:32Z 2021-10-27T19:56:32Z 2021 2021-09-14T15:34:01Z Article http://purl.org/eprint/type/JournalArticle https://hdl.handle.net/1721.1/133768 en 10.1016/J.ICARUS.2020.114072 Icarus Creative Commons Attribution-NonCommercial-NoDerivs License http://creativecommons.org/licenses/by-nc-nd/4.0/ application/pdf Elsevier BV arXiv
spellingShingle On the origin & thermal stability of Arrokoth's and Pluto's ices
title On the origin & thermal stability of Arrokoth's and Pluto's ices
title_full On the origin & thermal stability of Arrokoth's and Pluto's ices
title_fullStr On the origin & thermal stability of Arrokoth's and Pluto's ices
title_full_unstemmed On the origin & thermal stability of Arrokoth's and Pluto's ices
title_short On the origin & thermal stability of Arrokoth's and Pluto's ices
title_sort on the origin thermal stability of arrokoth s and pluto s ices
url https://hdl.handle.net/1721.1/133768