Modelling a hydrodynamic instability in freely settling colloidal gels
© 2018 Cambridge University Press. Attractive colloidal dispersions, suspensions of fine particles which aggregate and frequently form a space-spanning elastic gel are ubiquitous materials in society with a wide range of applications. The colloidal networks in these materials can exist in a mode of...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Cambridge University Press (CUP)
2021
|
| Online Access: | https://hdl.handle.net/1721.1/134758 |
| _version_ | 1826213465546555392 |
|---|---|
| author | Varga, Zsigmond Hofmann, Jennifer L Swan, James W |
| author_facet | Varga, Zsigmond Hofmann, Jennifer L Swan, James W |
| author_sort | Varga, Zsigmond |
| collection | MIT |
| description | © 2018 Cambridge University Press. Attractive colloidal dispersions, suspensions of fine particles which aggregate and frequently form a space-spanning elastic gel are ubiquitous materials in society with a wide range of applications. The colloidal networks in these materials can exist in a mode of free settling when the network weight exceeds its compressive yield stress. An equivalent state occurs when the network is held fixed in place and used as a filter through which the suspending fluid is pumped. In either scenario, hydrodynamic instabilities leading to loss of network integrity occur. Experimental observations have shown that the loss of integrity is associated with the formation of eroded channels, so-called streamers, through which the fluid flows rapidly. However, the dynamics of growth and subsequent mechanism of collapse remain poorly understood. Here, a phenomenological model is presented that describes dynamically the radial growth of a streamer due to erosion of the network by rapid fluid back flow. The model exhibits a finite-time blowup - the onset of catastrophic failure in the gel - due to activated breaking of the inter-colloid bonds. Brownian dynamics simulations of hydrodynamically interacting and settling colloids in dilute gels are employed to examine the initiation and propagation of this instability, which are in good agreement with the theory. The model dynamics is also shown to accurately replicate measurements of streamer growth in two different experimental systems. The predictive capabilities and future improvements of the model are discussed and a stability-state diagram is presented providing insight into engineering strategies for avoiding settling instabilities in networks meant to have long shelf lives. |
| first_indexed | 2024-09-23T15:49:38Z |
| format | Article |
| id | mit-1721.1/134758 |
| institution | Massachusetts Institute of Technology |
| language | English |
| last_indexed | 2024-09-23T15:49:38Z |
| publishDate | 2021 |
| publisher | Cambridge University Press (CUP) |
| record_format | dspace |
| spelling | mit-1721.1/1347582022-04-01T17:10:41Z Modelling a hydrodynamic instability in freely settling colloidal gels Varga, Zsigmond Hofmann, Jennifer L Swan, James W © 2018 Cambridge University Press. Attractive colloidal dispersions, suspensions of fine particles which aggregate and frequently form a space-spanning elastic gel are ubiquitous materials in society with a wide range of applications. The colloidal networks in these materials can exist in a mode of free settling when the network weight exceeds its compressive yield stress. An equivalent state occurs when the network is held fixed in place and used as a filter through which the suspending fluid is pumped. In either scenario, hydrodynamic instabilities leading to loss of network integrity occur. Experimental observations have shown that the loss of integrity is associated with the formation of eroded channels, so-called streamers, through which the fluid flows rapidly. However, the dynamics of growth and subsequent mechanism of collapse remain poorly understood. Here, a phenomenological model is presented that describes dynamically the radial growth of a streamer due to erosion of the network by rapid fluid back flow. The model exhibits a finite-time blowup - the onset of catastrophic failure in the gel - due to activated breaking of the inter-colloid bonds. Brownian dynamics simulations of hydrodynamically interacting and settling colloids in dilute gels are employed to examine the initiation and propagation of this instability, which are in good agreement with the theory. The model dynamics is also shown to accurately replicate measurements of streamer growth in two different experimental systems. The predictive capabilities and future improvements of the model are discussed and a stability-state diagram is presented providing insight into engineering strategies for avoiding settling instabilities in networks meant to have long shelf lives. 2021-10-27T20:09:00Z 2021-10-27T20:09:00Z 2018 2019-09-12T17:38:05Z Article http://purl.org/eprint/type/JournalArticle https://hdl.handle.net/1721.1/134758 en 10.1017/JFM.2018.725 Journal of Fluid Mechanics Creative Commons Attribution-Noncommercial-Share Alike http://creativecommons.org/licenses/by-nc-sa/4.0/ application/pdf Cambridge University Press (CUP) arXiv |
| spellingShingle | Varga, Zsigmond Hofmann, Jennifer L Swan, James W Modelling a hydrodynamic instability in freely settling colloidal gels |
| title | Modelling a hydrodynamic instability in freely settling colloidal gels |
| title_full | Modelling a hydrodynamic instability in freely settling colloidal gels |
| title_fullStr | Modelling a hydrodynamic instability in freely settling colloidal gels |
| title_full_unstemmed | Modelling a hydrodynamic instability in freely settling colloidal gels |
| title_short | Modelling a hydrodynamic instability in freely settling colloidal gels |
| title_sort | modelling a hydrodynamic instability in freely settling colloidal gels |
| url | https://hdl.handle.net/1721.1/134758 |
| work_keys_str_mv | AT vargazsigmond modellingahydrodynamicinstabilityinfreelysettlingcolloidalgels AT hofmannjenniferl modellingahydrodynamicinstabilityinfreelysettlingcolloidalgels AT swanjamesw modellingahydrodynamicinstabilityinfreelysettlingcolloidalgels |