Photodissociation transition states characterized by chirped pulse millimeter wave spectroscopy

Photodissociation transition states characterized by chirped pulse millimeter wave spectroscopy

© 2020 National Academy of Sciences. All rights reserved. The 193-nm photolysis of CH2CHCN illustrates the capability of chirped-pulse Fourier transform millimeter-wave spectroscopy to characterize transition states. We investigate the HCN, HNC photofragments in highly excited vibrational states usi...

Fuld beskrivelse

Bibliografiske detaljer
Main Authors:	Prozument, Kirill, Baraban, Joshua H, Changala, P Bryan, Park, G Barratt, Shaver, Rachel G, Muenter, John S, Klippenstein, Stephen J, Chernyak, Vladimir Y, Field, Robert W
Andre forfattere:	Massachusetts Institute of Technology. Department of Chemistry
Format:	Article
Sprog:	English
Udgivet:	Proceedings of the National Academy of Sciences 2021
Online adgang:	https://hdl.handle.net/1721.1/136575

Lignende værker

Chirped-Pulse Millimeter-Wave Spectroscopy of Rydberg-Rydberg Transitions
af: Prozument, Kirill, et al.
Udgivet: (2012)

Chirped-pulse millimeter-wave spectroscopy for dynamics and kinetics studies of pyrolysis reactions
af: Vasiliou, AnGayle K., et al.
Udgivet: (2018)

Chirped-pulse millimeter-wave spectroscopy: Spectrum, dynamics, and manipulation of Rydberg–Rydberg transitions
af: Colombo, Anthony P., et al.
Udgivet: (2014)

The use of chirped pulse millimeter-wave spectroscopy in chemical dynamics and kinetics
af: Shaver, Rachel Glyn
Udgivet: (2013)

Design and evaluation of a pulsed-jet chirped-pulse millimeter-wave spectrometer for the 70-102 GHz region
af: Park, Barratt, et al.
Udgivet: (2012)

Perspective: The first ten years of broadband chirped pulse Fourier transform microwave spectroscopy
af: Park, G. Barratt, et al.
Udgivet: (2017)

A Signature of Roaming Dynamics in the Thermal Decomposition of Ethyl Nitrite: Chirped-Pulse Rotational Spectroscopy and Kinetic Modeling
af: Prozument, Kirill, et al.
Udgivet: (2015)

Chirped-pulse millimeter-wave spectroscopy, dynamics, and manipulation of Rydberg-Rydberg Transitions
af: Colombo, Anthony P. (Anthony Paul)
Udgivet: (2013)

A chirped-pulse Fourier-transform microwave/pulsed uniform flow spectrometer. I. The low-temperature flow system
af: Oldham, James M., et al.
Udgivet: (2017)

A chirped-pulse Fourier-transform microwave/pulsed uniform flow spectrometer. II. Performance and applications for reaction dynamics
af: Abeysekera, Chamara, et al.
Udgivet: (2015)

A buffer gas cooled molecular beam apparatus for chirped pulse millimeter wave spectroscopy
af: Klein, Ethan Avram
Udgivet: (2015)

Edge effects in chirped-pulse Fourier transform microwave spectra
af: Park III, George Barratt, et al.
Udgivet: (2017)

Probing cis-trans isomerization in the S1 state of C2H2 via H-atom action and hot band-pumped IR-UV double resonance spectroscopies
af: Changala, P. Bryan, et al.
Udgivet: (2017)

Chirped ordered pulses for ultra-broadband ESR spectroscopy
af: Verstraete, J-B, et al.
Udgivet: (2021)

Increased sensitivity in electron–nuclear double resonance spectroscopy with chirped radiofrequency pulses
af: J. Stropp, et al.
Udgivet: (2025-01-01)

Product Branching in the Low Temperature Reaction of CN with Propyne by Chirped-Pulse Microwave Spectroscopy in a Uniform Supersonic Flow
af: Abeysekera, Chamara, et al.
Udgivet: (2016)

Near-threshold H/D exchange in CD₃CHO photodissociation.
af: Heazlewood, B, et al.
Udgivet: (2011)

Chirp Interference Mitigation in GNSS Systems Using Chirp Parameter Estimation and Pulse Blanking
af: Nabil Jardak
Udgivet: (2024-01-01)

Yb:CALYO-based femtosecond chirped pulse regenerative amplifier for temporally resolved pump-probe spectroscopy
af: A. S. Rudenkov, et al.
Udgivet: (2018-09-01)

Pulse compression with time-domain optimized chirped mirrors.
af: Dombi, P, et al.
Udgivet: (2005)

Generation and control of chirped, ultrafast pulse trains
af: O'Keeffe, K, et al.
Udgivet: (2010)

Double resonance spectroscopy reveals structure and dynamics near transition states
af: Joshua H. Baraban, et al.
Udgivet: (2025-01-01)

Spectroscopy and theory of cis-trans isomerization in the S₁ state of acetylene
af: Changala, P. Bryan (Peter Bryan)
Udgivet: (2013)

Photodissociation spectroscopy and dynamics of the vinoxy (CH2CHO) radical
af: Osborn, D, et al.
Udgivet: (1997)

A comparison of Chirp Diversity and Pulse Doppler Radar
af: Bernold, Dirk Matthew
Udgivet: (2007)

Reduced dimension rovibrational variational calculations of the S[subscript 1] state of C[subscript 2]H[subscript 2]. II. The S[subscript 1] rovibrational manifold and the effects of isomerization
af: Changala, Peter Bryan, et al.
Udgivet: (2015)

Full dimensional Franck-Condon factors for the acetylene [~ over A] [superscript 1]A[subscript u] — [~ over X] [superscript 1Σ[+ over g] transition. II. Vibrational overlap factors for levels involving excitation in ungerade modes
af: Baraban, Joshua H., et al.
Udgivet: (2015)

Effect of initial chirp on soliton pulse compression in the ionization regime
af: Wan, Ying, et al.
Udgivet: (2022)

The Effect of Chirped Intense Femtosecond Laser Pulses on the Argon Cluster
af: H. Ghaforyan, et al.
Udgivet: (2016-01-01)

The [~ over A][superscript 1]A[subscript u] state of acetylene: ungerade vibrational levels in the region 45,800-46,550 cm[superscript -1]
af: Merer, Anthony J., et al.
Udgivet: (2015)

All-Fiber-Based Ultrashort Pulse Generation and Chirped Pulse Amplification Through Parametric Processes
af: Zhou, Yue, et al.
Udgivet: (2012)

Ultrashort pulse characterization by spectral shearing interferometry with spatially chirped ancillae.
af: Witting, T, et al.
Udgivet: (2009)

Chirped pulse trains for quasi-phase-matching high harmonic generation
af: Robinson, T, et al.
Udgivet: (2009)

Spectral shearing interferometry with spatially chirped replicas for measuring ultrashort pulses.
af: Gorza, S, et al.
Udgivet: (2007)

Effects of chirped laser pulses on nonclassical correlations and entanglement of photon pairs
af: Ooi, Chong Heng Raymond
Udgivet: (2008)

Spectroscopic characterization of isomerization transition states
af: Mellau, Georg Ch., et al.
Udgivet: (2017)

High contrast multi-terawatt pulse generation using chirped pulse amplification on the VULCAN laser facility
af: Danson, C, et al.
Udgivet: (1993)

The vibrationally mediated photodissociation of Cl2.
af: Campbell, E, et al.
Udgivet: (2012)

Diazirine photodissociation and solvent effects
af: Goh, Chen Yee
Udgivet: (2023)

PHOTODISSOCIATION DYNAMICS OF HCOOH(A)
af: Brouard, M, et al.
Udgivet: (1988)