Physics of nanoscale immiscible fluid displacement

© 2019 American Physical Society. We investigate immiscible fluid displacement at small scales where slip lengths are on the order of characteristic system sizes, whereby Cox's law is not expected to be valid. Molecular dynamics simulations show that in this limit hydrodynamic bending becomes s...

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Main Authors: Wang, Gerald J, Damone, Angelo, Benfenati, Francesco, Poesio, Pietro, Beretta, Gian Paolo, Hadjiconstantinou, Nicolas G
Other Authors: Massachusetts Institute of Technology. Department of Mechanical Engineering
Format: Article
Language:English
Published: American Physical Society (APS) 2021
Online Access:https://hdl.handle.net/1721.1/136616
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author Wang, Gerald J
Damone, Angelo
Benfenati, Francesco
Poesio, Pietro
Beretta, Gian Paolo
Hadjiconstantinou, Nicolas G
author2 Massachusetts Institute of Technology. Department of Mechanical Engineering
author_facet Massachusetts Institute of Technology. Department of Mechanical Engineering
Wang, Gerald J
Damone, Angelo
Benfenati, Francesco
Poesio, Pietro
Beretta, Gian Paolo
Hadjiconstantinou, Nicolas G
author_sort Wang, Gerald J
collection MIT
description © 2019 American Physical Society. We investigate immiscible fluid displacement at small scales where slip lengths are on the order of characteristic system sizes, whereby Cox's law is not expected to be valid. Molecular dynamics simulations show that in this limit hydrodynamic bending becomes small and interfaces remain approximately spherical. In this case the only relevant angle for describing the interface shape is the dynamic microscopic angle at the fluid-solid interface. In our simulations, this angle is found to be described well by the molecular-kinetic theory originally proposed by Blake and Haynes. In general, this implies a different functional dependence between the contact angle (and related quantities) and the flow speed (or capillary number); this is demonstrated for the case of the force on the boundary for immiscible fluid displacement in a two-dimensional channel.
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spelling mit-1721.1/1366162023-03-15T17:28:22Z Physics of nanoscale immiscible fluid displacement Wang, Gerald J Damone, Angelo Benfenati, Francesco Poesio, Pietro Beretta, Gian Paolo Hadjiconstantinou, Nicolas G Massachusetts Institute of Technology. Department of Mechanical Engineering © 2019 American Physical Society. We investigate immiscible fluid displacement at small scales where slip lengths are on the order of characteristic system sizes, whereby Cox's law is not expected to be valid. Molecular dynamics simulations show that in this limit hydrodynamic bending becomes small and interfaces remain approximately spherical. In this case the only relevant angle for describing the interface shape is the dynamic microscopic angle at the fluid-solid interface. In our simulations, this angle is found to be described well by the molecular-kinetic theory originally proposed by Blake and Haynes. In general, this implies a different functional dependence between the contact angle (and related quantities) and the flow speed (or capillary number); this is demonstrated for the case of the force on the boundary for immiscible fluid displacement in a two-dimensional channel. 2021-10-27T20:36:15Z 2021-10-27T20:36:15Z 2019 2020-07-17T18:07:19Z Article http://purl.org/eprint/type/JournalArticle https://hdl.handle.net/1721.1/136616 en 10.1103/PHYSREVFLUIDS.4.124203 Physical Review Fluids Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Physical Society (APS) APS
spellingShingle Wang, Gerald J
Damone, Angelo
Benfenati, Francesco
Poesio, Pietro
Beretta, Gian Paolo
Hadjiconstantinou, Nicolas G
Physics of nanoscale immiscible fluid displacement
title Physics of nanoscale immiscible fluid displacement
title_full Physics of nanoscale immiscible fluid displacement
title_fullStr Physics of nanoscale immiscible fluid displacement
title_full_unstemmed Physics of nanoscale immiscible fluid displacement
title_short Physics of nanoscale immiscible fluid displacement
title_sort physics of nanoscale immiscible fluid displacement
url https://hdl.handle.net/1721.1/136616
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