Summary: | Spectroscopy in the mm/sub-mm wavelength range is a powerful tool to study the gaseous medium in various astrophysical environments. The next generation Event Horizon Telescope (ngEHT) equipped with a wide-bandwidth backend system has great potential for science using high angular resolution spectroscopy. Spectral line VLBI studies using the ngEHT will enable us to scrutinize compact astrophysical objects obscured by an optically thick medium on unprecedented angular scales. However, the capabilities of ngEHT for spectroscopy and specific scientific applications have not been properly envisioned. In this white paper, we briefly address science cases newly achievable via spectral line VLBI observations in the mm/sub-mm wavelength ranges, and suggest technical requirements to facilitate spectral line VLBI studies in the ngEHT era.
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