Studies on Organophosphorus Catalyzed C(SP³)–H Amination for the Synthesis of Benzimidazoles

Studies on Organophosphorus Catalyzed C(SP³)–H Amination for the Synthesis of Benzimidazoles

A PIII/PV=O-catalyzed C(sp³)–H amination has been realized for (dihydro)benzimidazole synthesis. This work reports: (1) optimization of organophosphorus-catalyzed C(sp³)–H functionalization; (2) scope studies to benzimidazoles by in situ oxidation of the corresponding dihydrobenzimidazole; and (3) i...

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Bibliographic Details
Main Author:	Pombar, Gisselle
Other Authors:	Radosevich, Alexander T.
Format:	Thesis
Published:	Massachusetts Institute of Technology 2023
Online Access:	https://hdl.handle.net/1721.1/147263

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