Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit
We report a metal-organic framework (MOF) with a rare two-dimensional (2D) secondary building unit (SBU). The SBU comprises mixed-valent Fe2+ and Fe3+ metal ions bridged by oxygen atoms pertaining to the polytopic ligand 3,3',4,4',5,5'-hexahydroxybiphenyl, which also define the iron-o...
| Main Authors: | , , , , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2023
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| Online Access: | https://hdl.handle.net/1721.1/148036 |
| _version_ | 1826200706326986752 |
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| author | Kampouri, Stavroula Zhang, Mingxuan Chen, Tianyang Oppenheim, Julius J Brown, Alexandra Payne, Michael Andrews, Justin L Sun, Junliang Dincă, Mircea |
| author2 | Massachusetts Institute of Technology. Department of Chemistry |
| author_facet | Massachusetts Institute of Technology. Department of Chemistry Kampouri, Stavroula Zhang, Mingxuan Chen, Tianyang Oppenheim, Julius J Brown, Alexandra Payne, Michael Andrews, Justin L Sun, Junliang Dincă, Mircea |
| author_sort | Kampouri, Stavroula |
| collection | MIT |
| description | We report a metal-organic framework (MOF) with a rare two-dimensional (2D) secondary building unit (SBU). The SBU comprises mixed-valent Fe2+ and Fe3+ metal ions bridged by oxygen atoms pertaining to the polytopic ligand 3,3',4,4',5,5'-hexahydroxybiphenyl, which also define the iron-oxide 2D layers. Overall, the anionic framework exhibits rare topology and evidences strong electronic communication between the mixed-valence iron sites. These results highlight the importance of dimensionality control of MOF SBUs for discovering new topologies in reticular chemistry, and especially for improving electronic communication within the MOF skeleton. |
| first_indexed | 2024-09-23T11:40:35Z |
| format | Article |
| id | mit-1721.1/148036 |
| institution | Massachusetts Institute of Technology |
| language | English |
| last_indexed | 2024-09-23T11:40:35Z |
| publishDate | 2023 |
| publisher | Wiley |
| record_format | dspace |
| spelling | mit-1721.1/1480362023-02-15T03:29:42Z Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit Kampouri, Stavroula Zhang, Mingxuan Chen, Tianyang Oppenheim, Julius J Brown, Alexandra Payne, Michael Andrews, Justin L Sun, Junliang Dincă, Mircea Massachusetts Institute of Technology. Department of Chemistry We report a metal-organic framework (MOF) with a rare two-dimensional (2D) secondary building unit (SBU). The SBU comprises mixed-valent Fe2+ and Fe3+ metal ions bridged by oxygen atoms pertaining to the polytopic ligand 3,3',4,4',5,5'-hexahydroxybiphenyl, which also define the iron-oxide 2D layers. Overall, the anionic framework exhibits rare topology and evidences strong electronic communication between the mixed-valence iron sites. These results highlight the importance of dimensionality control of MOF SBUs for discovering new topologies in reticular chemistry, and especially for improving electronic communication within the MOF skeleton. 2023-02-14T14:54:16Z 2023-02-14T14:54:16Z 2022 2023-02-14T14:45:55Z Article http://purl.org/eprint/type/JournalArticle https://hdl.handle.net/1721.1/148036 Kampouri, Stavroula, Zhang, Mingxuan, Chen, Tianyang, Oppenheim, Julius J, Brown, Alexandra et al. 2022. "Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit." Angewandte Chemie - International Edition, 61 (49). en 10.1002/ANIE.202213960 Angewandte Chemie - International Edition Creative Commons Attribution-NonCommercial-NoDerivs License http://creativecommons.org/licenses/by-nc-nd/4.0/ application/pdf Wiley Wiley |
| spellingShingle | Kampouri, Stavroula Zhang, Mingxuan Chen, Tianyang Oppenheim, Julius J Brown, Alexandra Payne, Michael Andrews, Justin L Sun, Junliang Dincă, Mircea Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit |
| title | Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit |
| title_full | Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit |
| title_fullStr | Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit |
| title_full_unstemmed | Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit |
| title_short | Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit |
| title_sort | pyrogallate based metal organic framework with a two dimensional secondary building unit |
| url | https://hdl.handle.net/1721.1/148036 |
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