| Summary: | With the surge of electric vehicles, fast charging has become one of the major challenges for the development of Li-ion and Li metal batteries. The degradation of battery electrodes at fast charging has been identified as among the gating factors. While there have been extensive studies on anode and cathode degradation modes, not sufficient efforts have been made to dive deep into the kinetics of battery charging and its influence on electrode degradation, especially during fast charging. This review presents a comprehensive yet concentrated perspective into such issues. By tracing back to the kinetic origins of battery charging, it is revealed that the intrinsic properties of electrode active materials and the microstructures of electrode are of great importance in determining electrode kinetics. Most of the electrode degradation modes are closely related to the high overpotentials and the spatial inhomogeneity in Li concentration and pertinent characteristics, which are results of the sluggish electrode kinetics during fast charging. Approaches to mitigate electrode degradation are summarized from the aspect of improving electrode kinetics and circumventing detrimental side reactions.
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