Review on Electrode Degradation at Fast Charging of Li-Ion and Li Metal Batteries from a Kinetic Perspective
With the surge of electric vehicles, fast charging has become one of the major challenges for the development of Li-ion and Li metal batteries. The degradation of battery electrodes at fast charging has been identified as among the gating factors. While there have been extensive studies on anode and...
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| Format: | Article |
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Multidisciplinary Digital Publishing Institute
2023
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| Online Access: | https://hdl.handle.net/1721.1/149837 |
| _version_ | 1826201929776103424 |
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| author | Miao, Jinghui |
| author2 | Massachusetts Institute of Technology. Department of Materials Science and Engineering |
| author_facet | Massachusetts Institute of Technology. Department of Materials Science and Engineering Miao, Jinghui |
| author_sort | Miao, Jinghui |
| collection | MIT |
| description | With the surge of electric vehicles, fast charging has become one of the major challenges for the development of Li-ion and Li metal batteries. The degradation of battery electrodes at fast charging has been identified as among the gating factors. While there have been extensive studies on anode and cathode degradation modes, not sufficient efforts have been made to dive deep into the kinetics of battery charging and its influence on electrode degradation, especially during fast charging. This review presents a comprehensive yet concentrated perspective into such issues. By tracing back to the kinetic origins of battery charging, it is revealed that the intrinsic properties of electrode active materials and the microstructures of electrode are of great importance in determining electrode kinetics. Most of the electrode degradation modes are closely related to the high overpotentials and the spatial inhomogeneity in Li concentration and pertinent characteristics, which are results of the sluggish electrode kinetics during fast charging. Approaches to mitigate electrode degradation are summarized from the aspect of improving electrode kinetics and circumventing detrimental side reactions. |
| first_indexed | 2024-09-23T11:59:06Z |
| format | Article |
| id | mit-1721.1/149837 |
| institution | Massachusetts Institute of Technology |
| last_indexed | 2024-09-23T11:59:06Z |
| publishDate | 2023 |
| publisher | Multidisciplinary Digital Publishing Institute |
| record_format | dspace |
| spelling | mit-1721.1/1498372024-01-29T21:14:19Z Review on Electrode Degradation at Fast Charging of Li-Ion and Li Metal Batteries from a Kinetic Perspective Miao, Jinghui Massachusetts Institute of Technology. Department of Materials Science and Engineering With the surge of electric vehicles, fast charging has become one of the major challenges for the development of Li-ion and Li metal batteries. The degradation of battery electrodes at fast charging has been identified as among the gating factors. While there have been extensive studies on anode and cathode degradation modes, not sufficient efforts have been made to dive deep into the kinetics of battery charging and its influence on electrode degradation, especially during fast charging. This review presents a comprehensive yet concentrated perspective into such issues. By tracing back to the kinetic origins of battery charging, it is revealed that the intrinsic properties of electrode active materials and the microstructures of electrode are of great importance in determining electrode kinetics. Most of the electrode degradation modes are closely related to the high overpotentials and the spatial inhomogeneity in Li concentration and pertinent characteristics, which are results of the sluggish electrode kinetics during fast charging. Approaches to mitigate electrode degradation are summarized from the aspect of improving electrode kinetics and circumventing detrimental side reactions. 2023-03-29T15:28:08Z 2023-03-29T15:28:08Z 2023-03-23 2023-03-28T12:56:00Z Article http://purl.org/eprint/type/JournalArticle https://hdl.handle.net/1721.1/149837 Electrochem 4 (2): 156-180 (2023) PUBLISHER_CC http://dx.doi.org/10.3390/electrochem4020013 Creative Commons Attribution https://creativecommons.org/licenses/by/4.0/ application/pdf Multidisciplinary Digital Publishing Institute Multidisciplinary Digital Publishing Institute |
| spellingShingle | Miao, Jinghui Review on Electrode Degradation at Fast Charging of Li-Ion and Li Metal Batteries from a Kinetic Perspective |
| title | Review on Electrode Degradation at Fast Charging of Li-Ion and Li Metal Batteries from a Kinetic Perspective |
| title_full | Review on Electrode Degradation at Fast Charging of Li-Ion and Li Metal Batteries from a Kinetic Perspective |
| title_fullStr | Review on Electrode Degradation at Fast Charging of Li-Ion and Li Metal Batteries from a Kinetic Perspective |
| title_full_unstemmed | Review on Electrode Degradation at Fast Charging of Li-Ion and Li Metal Batteries from a Kinetic Perspective |
| title_short | Review on Electrode Degradation at Fast Charging of Li-Ion and Li Metal Batteries from a Kinetic Perspective |
| title_sort | review on electrode degradation at fast charging of li ion and li metal batteries from a kinetic perspective |
| url | https://hdl.handle.net/1721.1/149837 |
| work_keys_str_mv | AT miaojinghui reviewonelectrodedegradationatfastchargingofliionandlimetalbatteriesfromakineticperspective |