Quantitative assessment of the frictional ignition resistance of metals in high-pressure oxygen
In this work, we developed a material index for selecting alloys resistant to frictional ignition in high-pressure oxygen environments. A previous ignition-resistance metric proposed by NASA WSTF varies strongly and unpredictably with test conditions, thus limiting its usefulness. The material index...
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| Format: | Thesis |
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Massachusetts Institute of Technology
2023
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| Online Access: | https://hdl.handle.net/1721.1/151658 |
| _version_ | 1826203401455665152 |
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| author | Garcia Jimenez, Andres |
| author2 | Cordero, Zachary C. |
| author_facet | Cordero, Zachary C. Garcia Jimenez, Andres |
| author_sort | Garcia Jimenez, Andres |
| collection | MIT |
| description | In this work, we developed a material index for selecting alloys resistant to frictional ignition in high-pressure oxygen environments. A previous ignition-resistance metric proposed by NASA WSTF varies strongly and unpredictably with test conditions, thus limiting its usefulness. The material index developed here incorporates key material properties that influence ignition behaviors, including friction coefficient, ignition temperature, and thermal effusivity. Finite element simulations were used to compute ignition temperatures for 15 alloys based on published frictional ignition data from NASA White Sands Testing Facility (WSTF). These values were used with the material index to construct property diagrams for ranking intrinsic frictional ignition resistance. The results demonstrate that nickel-based superalloys with low iron content are less likely to ignite under frictional heating than ferrous alloys and nickel-based superalloys with high content iron. The material index is then used to predict material performance outside of the test conditions, highlighting the effect of ambient temperature on ignition resistance. We conclude by developing an empirical relation between ignition temperature and enthalpy of oxidation which can guide the design of new ignition-resistant alloys. |
| first_indexed | 2024-09-23T12:36:00Z |
| format | Thesis |
| id | mit-1721.1/151658 |
| institution | Massachusetts Institute of Technology |
| last_indexed | 2024-09-23T12:36:00Z |
| publishDate | 2023 |
| publisher | Massachusetts Institute of Technology |
| record_format | dspace |
| spelling | mit-1721.1/1516582023-08-01T03:44:35Z Quantitative assessment of the frictional ignition resistance of metals in high-pressure oxygen Garcia Jimenez, Andres Cordero, Zachary C. Massachusetts Institute of Technology. Department of Aeronautics and Astronautics In this work, we developed a material index for selecting alloys resistant to frictional ignition in high-pressure oxygen environments. A previous ignition-resistance metric proposed by NASA WSTF varies strongly and unpredictably with test conditions, thus limiting its usefulness. The material index developed here incorporates key material properties that influence ignition behaviors, including friction coefficient, ignition temperature, and thermal effusivity. Finite element simulations were used to compute ignition temperatures for 15 alloys based on published frictional ignition data from NASA White Sands Testing Facility (WSTF). These values were used with the material index to construct property diagrams for ranking intrinsic frictional ignition resistance. The results demonstrate that nickel-based superalloys with low iron content are less likely to ignite under frictional heating than ferrous alloys and nickel-based superalloys with high content iron. The material index is then used to predict material performance outside of the test conditions, highlighting the effect of ambient temperature on ignition resistance. We conclude by developing an empirical relation between ignition temperature and enthalpy of oxidation which can guide the design of new ignition-resistant alloys. S.M. 2023-07-31T19:56:59Z 2023-07-31T19:56:59Z 2023-06 2023-06-16T11:27:45.697Z Thesis https://hdl.handle.net/1721.1/151658 Attribution 4.0 International (CC BY 4.0) Copyright retained by author(s) https://creativecommons.org/licenses/by/4.0/ application/pdf Massachusetts Institute of Technology |
| spellingShingle | Garcia Jimenez, Andres Quantitative assessment of the frictional ignition resistance of metals in high-pressure oxygen |
| title | Quantitative assessment of the frictional ignition resistance of
metals in high-pressure oxygen |
| title_full | Quantitative assessment of the frictional ignition resistance of
metals in high-pressure oxygen |
| title_fullStr | Quantitative assessment of the frictional ignition resistance of
metals in high-pressure oxygen |
| title_full_unstemmed | Quantitative assessment of the frictional ignition resistance of
metals in high-pressure oxygen |
| title_short | Quantitative assessment of the frictional ignition resistance of
metals in high-pressure oxygen |
| title_sort | quantitative assessment of the frictional ignition resistance of metals in high pressure oxygen |
| url | https://hdl.handle.net/1721.1/151658 |
| work_keys_str_mv | AT garciajimenezandres quantitativeassessmentofthefrictionalignitionresistanceofmetalsinhighpressureoxygen |