Site-selective Labeling of the Nitrogenase Iron-Molybdenum Cofactor
Nitrogenases are enzymes known to catalyze the kinetically challenging, and biologically important, reduction of N₂ to NH₃. The mechanism of these enzymes, and in particular, the chemistry that occurs at the catalytic cofactor of the Mo nitrogenase, the iron- molybdenum cofactor (FeMo-co), has been...
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Massachusetts Institute of Technology
2023
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| Online Access: | https://hdl.handle.net/1721.1/152119 https://orcid.org/0000-0001-6551-5185 |