Building block 3D printing based on molecular self-assembly monolayer with self-healing properties

<jats:title>Abstract</jats:title><jats:p>The spontaneous formation of biological substances, such as human organs, are governed by different stimuli driven by complex 3D self-organization protocols at the molecular level. The fundamentals of such molecular self-assembly processes a...

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Main Authors: Hamoudi, Hicham, Berdiyorov, Golibjon R, Zekri, Atef, Tong, Yongfeng, Mansour, Said, Esaulov, Vladimir A, Youcef-Toumi, Kamal
Other Authors: Massachusetts Institute of Technology. Department of Mechanical Engineering
Format: Article
Language:English
Published: Springer Science and Business Media LLC 2024
Online Access:https://hdl.handle.net/1721.1/153608
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author Hamoudi, Hicham
Berdiyorov, Golibjon R
Zekri, Atef
Tong, Yongfeng
Mansour, Said
Esaulov, Vladimir A
Youcef-Toumi, Kamal
author2 Massachusetts Institute of Technology. Department of Mechanical Engineering
author_facet Massachusetts Institute of Technology. Department of Mechanical Engineering
Hamoudi, Hicham
Berdiyorov, Golibjon R
Zekri, Atef
Tong, Yongfeng
Mansour, Said
Esaulov, Vladimir A
Youcef-Toumi, Kamal
author_sort Hamoudi, Hicham
collection MIT
description <jats:title>Abstract</jats:title><jats:p>The spontaneous formation of biological substances, such as human organs, are governed by different stimuli driven by complex 3D self-organization protocols at the molecular level. The fundamentals of such molecular self-assembly processes are critical for fabrication of advanced technological components in nature. We propose and experimentally demonstrate a promising 3D printing method with self-healing property based on molecular self-assembly-monolayer principles, which is conceptually different than the existing 3D printing protocols. The proposed molecular building-block approach uses metal ion-mediated continuous self-assembly of organic molecular at liquid–liquid interfaces to create 2D and 3D structures. Using this technique, we directly printed nanosheets and 3D rods using dithiol molecules as building block units.</jats:p>
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spelling mit-1721.1/1536082024-03-01T03:37:02Z Building block 3D printing based on molecular self-assembly monolayer with self-healing properties Hamoudi, Hicham Berdiyorov, Golibjon R Zekri, Atef Tong, Yongfeng Mansour, Said Esaulov, Vladimir A Youcef-Toumi, Kamal Massachusetts Institute of Technology. Department of Mechanical Engineering <jats:title>Abstract</jats:title><jats:p>The spontaneous formation of biological substances, such as human organs, are governed by different stimuli driven by complex 3D self-organization protocols at the molecular level. The fundamentals of such molecular self-assembly processes are critical for fabrication of advanced technological components in nature. We propose and experimentally demonstrate a promising 3D printing method with self-healing property based on molecular self-assembly-monolayer principles, which is conceptually different than the existing 3D printing protocols. The proposed molecular building-block approach uses metal ion-mediated continuous self-assembly of organic molecular at liquid–liquid interfaces to create 2D and 3D structures. Using this technique, we directly printed nanosheets and 3D rods using dithiol molecules as building block units.</jats:p> 2024-02-29T13:33:35Z 2024-02-29T13:33:35Z 2022 2024-02-29T13:30:27Z Article http://purl.org/eprint/type/JournalArticle https://hdl.handle.net/1721.1/153608 Hamoudi, Hicham, Berdiyorov, Golibjon R, Zekri, Atef, Tong, Yongfeng, Mansour, Said et al. 2022. "Building block 3D printing based on molecular self-assembly monolayer with self-healing properties." Scientific Reports, 12 (1). en 10.1038/s41598-022-10875-9 Scientific Reports Creative Commons Attribution http://creativecommons.org/licenses/by/4.0/ application/pdf Springer Science and Business Media LLC Nature
spellingShingle Hamoudi, Hicham
Berdiyorov, Golibjon R
Zekri, Atef
Tong, Yongfeng
Mansour, Said
Esaulov, Vladimir A
Youcef-Toumi, Kamal
Building block 3D printing based on molecular self-assembly monolayer with self-healing properties
title Building block 3D printing based on molecular self-assembly monolayer with self-healing properties
title_full Building block 3D printing based on molecular self-assembly monolayer with self-healing properties
title_fullStr Building block 3D printing based on molecular self-assembly monolayer with self-healing properties
title_full_unstemmed Building block 3D printing based on molecular self-assembly monolayer with self-healing properties
title_short Building block 3D printing based on molecular self-assembly monolayer with self-healing properties
title_sort building block 3d printing based on molecular self assembly monolayer with self healing properties
url https://hdl.handle.net/1721.1/153608
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