Unified quantum theory of electrochemical kinetics by coupled ion–electron transfer
A general theory of coupled ion–electron transfer (CIET) is presented, which unifies Marcus kinetics of electron transfer (ET) with Butler–Volmer kinetics of ion transfer (IT). In the limit of large reorganization energy, the theory predicts normal Marcus kinetics of “electron-coupled ion transfer”...
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| Format: | Article |
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Royal Society of Chemistry
2024
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| Online Access: | https://hdl.handle.net/1721.1/154129 |