Two-Dimensional Self-Assembly in Diblock Copolymers
Submitted to Phys. Rev. Lett.
Main Authors: | , , , , |
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Format: | Preprint |
Language: | en_US |
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2005
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Online Access: | http://hdl.handle.net/1721.1/18153 |
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author | Hosoi, A.E. Kogan, Dmitriy Devereaux, C.E. Bernoff, Andrew J. Baker, S.M. |
author_facet | Hosoi, A.E. Kogan, Dmitriy Devereaux, C.E. Bernoff, Andrew J. Baker, S.M. |
author_sort | Hosoi, A.E. |
collection | MIT |
description | Submitted to Phys. Rev. Lett. |
first_indexed | 2024-09-23T16:21:09Z |
format | Preprint |
id | mit-1721.1/18153 |
institution | Massachusetts Institute of Technology |
language | en_US |
last_indexed | 2024-09-23T16:21:09Z |
publishDate | 2005 |
record_format | dspace |
spelling | mit-1721.1/181532019-04-12T08:40:55Z Two-Dimensional Self-Assembly in Diblock Copolymers Hosoi, A.E. Kogan, Dmitriy Devereaux, C.E. Bernoff, Andrew J. Baker, S.M. Diblock copolymers Self-assembly 2D pattern formation Submitted to Phys. Rev. Lett. Diblock copolymers confined to a two-dimensional surface may produce uniform features of macromolecular dimensions (10 â 100 nm). We present a mathematical model for nanoscale pattern formation in such polymers which captures the dynamic evolution of a solution of poly(styrene)- b-poly(ethylene oxide), PS-b-PEO, in solvent at an air-water interface. The model has no fitting parameters and incorporates the effects of surface tension gradients, entanglement or vitrification, and diffusion. The resultant morphologies are quantitatively compared with experimental data. NSF 2005-06-20T20:01:31Z 2005-06-20T20:01:31Z 2005-06-20T20:01:31Z Preprint http://hdl.handle.net/1721.1/18153 en_US 05-P-07; 586974 bytes application/pdf application/pdf |
spellingShingle | Diblock copolymers Self-assembly 2D pattern formation Hosoi, A.E. Kogan, Dmitriy Devereaux, C.E. Bernoff, Andrew J. Baker, S.M. Two-Dimensional Self-Assembly in Diblock Copolymers |
title | Two-Dimensional Self-Assembly in Diblock Copolymers |
title_full | Two-Dimensional Self-Assembly in Diblock Copolymers |
title_fullStr | Two-Dimensional Self-Assembly in Diblock Copolymers |
title_full_unstemmed | Two-Dimensional Self-Assembly in Diblock Copolymers |
title_short | Two-Dimensional Self-Assembly in Diblock Copolymers |
title_sort | two dimensional self assembly in diblock copolymers |
topic | Diblock copolymers Self-assembly 2D pattern formation |
url | http://hdl.handle.net/1721.1/18153 |
work_keys_str_mv | AT hosoiae twodimensionalselfassemblyindiblockcopolymers AT kogandmitriy twodimensionalselfassemblyindiblockcopolymers AT devereauxce twodimensionalselfassemblyindiblockcopolymers AT bernoffandrewj twodimensionalselfassemblyindiblockcopolymers AT bakersm twodimensionalselfassemblyindiblockcopolymers |