A continuum theory of amorphous solids undergoing large deformations, with application to polymeric glasses

This paper summarizes a recently developed continuum theory for the elastic-viscoplastic deformation of amorphous solids such as polymeric and metallic glasses. Introducing an internal-state variable that represents the local free-volume associated with certain metastable states, we are able to capt...

Ausführliche Beschreibung

Bibliographische Detailangaben
1. Verfasser: Anand, Lallit
Format: Artikel
Sprache:en_US
Veröffentlicht: 2003
Schlagworte:
Online Zugang:http://hdl.handle.net/1721.1/3660
_version_ 1826213731233693696
author Anand, Lallit
author_facet Anand, Lallit
author_sort Anand, Lallit
collection MIT
description This paper summarizes a recently developed continuum theory for the elastic-viscoplastic deformation of amorphous solids such as polymeric and metallic glasses. Introducing an internal-state variable that represents the local free-volume associated with certain metastable states, we are able to capture the highly non-linear stress-strain behavior that precedes the yield-peak and gives rise to post-yield strain-softening. Our theory explicitly accounts for the dependence of the Helmholtz free energy on the plastic deformation in a thermodynamically consistent manner. This dependence leads directly to a backstress in the underlying flow rule, and allows us to model the rapid strain-hardening response after the initial yield-drop in monotonic deformations, as well as the Bauschinger-type reverse-yielding phenomena typically observed in amorphous polymeric solids upon unloading after large plastic deformations. We have implemented a special set of constitutive equations resulting from the general theory in a finite-element computer program. Using this finite-element program, we apply the specialized equations to model the large-deformation response of the amorphous polymeric solid polycarbonate, at ambient temperature and pressure. We show numerical results to some representative problems, and compare them against corresponding results from physical experiments.
first_indexed 2024-09-23T15:53:55Z
format Article
id mit-1721.1/3660
institution Massachusetts Institute of Technology
language en_US
last_indexed 2024-09-23T15:53:55Z
publishDate 2003
record_format dspace
spelling mit-1721.1/36602019-04-10T12:16:16Z A continuum theory of amorphous solids undergoing large deformations, with application to polymeric glasses Anand, Lallit amorphous solids metallic glasses plasticity polymeric glasses This paper summarizes a recently developed continuum theory for the elastic-viscoplastic deformation of amorphous solids such as polymeric and metallic glasses. Introducing an internal-state variable that represents the local free-volume associated with certain metastable states, we are able to capture the highly non-linear stress-strain behavior that precedes the yield-peak and gives rise to post-yield strain-softening. Our theory explicitly accounts for the dependence of the Helmholtz free energy on the plastic deformation in a thermodynamically consistent manner. This dependence leads directly to a backstress in the underlying flow rule, and allows us to model the rapid strain-hardening response after the initial yield-drop in monotonic deformations, as well as the Bauschinger-type reverse-yielding phenomena typically observed in amorphous polymeric solids upon unloading after large plastic deformations. We have implemented a special set of constitutive equations resulting from the general theory in a finite-element computer program. Using this finite-element program, we apply the specialized equations to model the large-deformation response of the amorphous polymeric solid polycarbonate, at ambient temperature and pressure. We show numerical results to some representative problems, and compare them against corresponding results from physical experiments. Singapore-MIT Alliance (SMA) 2003-11-10T19:24:07Z 2003-11-10T19:24:07Z 2003-01 Article http://hdl.handle.net/1721.1/3660 en_US Advanced Materials for Micro- and Nano-Systems (AMMNS); 211086 bytes application/pdf application/pdf
spellingShingle amorphous solids
metallic glasses
plasticity
polymeric glasses
Anand, Lallit
A continuum theory of amorphous solids undergoing large deformations, with application to polymeric glasses
title A continuum theory of amorphous solids undergoing large deformations, with application to polymeric glasses
title_full A continuum theory of amorphous solids undergoing large deformations, with application to polymeric glasses
title_fullStr A continuum theory of amorphous solids undergoing large deformations, with application to polymeric glasses
title_full_unstemmed A continuum theory of amorphous solids undergoing large deformations, with application to polymeric glasses
title_short A continuum theory of amorphous solids undergoing large deformations, with application to polymeric glasses
title_sort continuum theory of amorphous solids undergoing large deformations with application to polymeric glasses
topic amorphous solids
metallic glasses
plasticity
polymeric glasses
url http://hdl.handle.net/1721.1/3660
work_keys_str_mv AT anandlallit acontinuumtheoryofamorphoussolidsundergoinglargedeformationswithapplicationtopolymericglasses
AT anandlallit continuumtheoryofamorphoussolidsundergoinglargedeformationswithapplicationtopolymericglasses