Tuning the photophysical properties of amidophosphine complexes of copper
Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2009.
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| Format: | Thesis |
| Language: | eng |
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Massachusetts Institute of Technology
2009
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| Online Access: | http://hdl.handle.net/1721.1/49753 |
| _version_ | 1826199658475552768 |
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| author | Mickenberg, Seth F. (Seth Fox) |
| author2 | Jonas C. Peters. |
| author_facet | Jonas C. Peters. Mickenberg, Seth F. (Seth Fox) |
| author_sort | Mickenberg, Seth F. (Seth Fox) |
| collection | MIT |
| description | Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2009. |
| first_indexed | 2024-09-23T11:23:47Z |
| format | Thesis |
| id | mit-1721.1/49753 |
| institution | Massachusetts Institute of Technology |
| language | eng |
| last_indexed | 2024-09-23T11:23:47Z |
| publishDate | 2009 |
| publisher | Massachusetts Institute of Technology |
| record_format | dspace |
| spelling | mit-1721.1/497532019-04-12T13:43:17Z Tuning the photophysical properties of amidophosphine complexes of copper Mickenberg, Seth F. (Seth Fox) Jonas C. Peters. Massachusetts Institute of Technology. Dept. of Chemistry. Massachusetts Institute of Technology. Dept. of Chemistry. Chemistry. Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2009. Vita. Includes bibliographical references (leaves 23-24). A series of monomeric copper complexes that allow for the tuning of the emission properties is reported. Luminescence lifetimes up to 150 [mu]s are observed in benzene solution at ambient temperature, which are comparable to the lifetimes of the longest-lived previously reported copper luminophores. These complexes also exhibit quantum yields up to 0 = 0.70 at 298 K. The results of time-dependent density functional theory (TDDFT) calculations indicate emission from a triplet state in all cases. The calculations also successfully correlate the energy of the transition from this triplet state to the energy of the observed emission. Such luminescence from a first-row metal is highly unusual, especially when considering the phosphine-based ligand framework used. by Seth F. Mickenberg. S.M. 2009-11-06T16:30:00Z 2009-11-06T16:30:00Z 2009 2009 Thesis http://hdl.handle.net/1721.1/49753 456703892 eng M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. http://dspace.mit.edu/handle/1721.1/7582 26 leaves application/pdf Massachusetts Institute of Technology |
| spellingShingle | Chemistry. Mickenberg, Seth F. (Seth Fox) Tuning the photophysical properties of amidophosphine complexes of copper |
| title | Tuning the photophysical properties of amidophosphine complexes of copper |
| title_full | Tuning the photophysical properties of amidophosphine complexes of copper |
| title_fullStr | Tuning the photophysical properties of amidophosphine complexes of copper |
| title_full_unstemmed | Tuning the photophysical properties of amidophosphine complexes of copper |
| title_short | Tuning the photophysical properties of amidophosphine complexes of copper |
| title_sort | tuning the photophysical properties of amidophosphine complexes of copper |
| topic | Chemistry. |
| url | http://hdl.handle.net/1721.1/49753 |
| work_keys_str_mv | AT mickenbergsethfsethfox tuningthephotophysicalpropertiesofamidophosphinecomplexesofcopper |