Dinitrogen and organometallic chemistry of trimethylsilyl-substituted triamidoamine complexes of molybdenum
Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 1999.
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| Format: | Thesis |
| Language: | eng |
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Massachusetts Institute of Technology
2010
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| Online Access: | http://hdl.handle.net/1721.1/50544 |
| _version_ | 1826216843955666944 |
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| author | O'Donoghue, Myra Brigid, 1966- |
| author2 | Richard R. Shrock. |
| author_facet | Richard R. Shrock. O'Donoghue, Myra Brigid, 1966- |
| author_sort | O'Donoghue, Myra Brigid, 1966- |
| collection | MIT |
| description | Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 1999. |
| first_indexed | 2024-09-23T16:54:01Z |
| format | Thesis |
| id | mit-1721.1/50544 |
| institution | Massachusetts Institute of Technology |
| language | eng |
| last_indexed | 2024-09-23T16:54:01Z |
| publishDate | 2010 |
| publisher | Massachusetts Institute of Technology |
| record_format | dspace |
| spelling | mit-1721.1/505442019-09-19T21:29:57Z Dinitrogen and organometallic chemistry of trimethylsilyl-substituted triamidoamine complexes of molybdenum O'Donoghue, Myra Brigid, 1966- Richard R. Shrock. Massachusetts Institute of Technology. Dept. of Chemistry. Massachusetts Institute of Technology. Department of Chemistry Chemistry. Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 1999. Includes bibliographical references. { [N 3N]Mo-N=N} 2Mg(THF)2, isolated from the reduction of [N3N]MoCl by magnesium powder under dinitrogen, serves as an entry into the dinitrogen chemistry of molybdenum complexes containing the TMS-TREN ligand. ... Five coordinate tungsten oxo alkylidene complexes of the general type (ArO)2W(O)(CHtBu)(PR 3 ) (Ar = 2,6-Ph2C6H3 ) are synthesized by reaction of Ta(CHtBu)(PR 3)2X3 (X = Cl, Br) with W(O)(OtBu) 4. 1H NMR spectroscopy reveals that only the syn rotamer is present in solution and PPh2Me is labile on the NMR time scale. by Myra Brigid O'Donoghue. Ph.D. 2010-01-07T20:51:16Z 2010-01-07T20:51:16Z 1999 1999 Thesis http://hdl.handle.net/1721.1/50544 43852050 eng M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. http://dspace.mit.edu/handle/1721.1/7582 178 leaves application/pdf Massachusetts Institute of Technology |
| spellingShingle | Chemistry. O'Donoghue, Myra Brigid, 1966- Dinitrogen and organometallic chemistry of trimethylsilyl-substituted triamidoamine complexes of molybdenum |
| title | Dinitrogen and organometallic chemistry of trimethylsilyl-substituted triamidoamine complexes of molybdenum |
| title_full | Dinitrogen and organometallic chemistry of trimethylsilyl-substituted triamidoamine complexes of molybdenum |
| title_fullStr | Dinitrogen and organometallic chemistry of trimethylsilyl-substituted triamidoamine complexes of molybdenum |
| title_full_unstemmed | Dinitrogen and organometallic chemistry of trimethylsilyl-substituted triamidoamine complexes of molybdenum |
| title_short | Dinitrogen and organometallic chemistry of trimethylsilyl-substituted triamidoamine complexes of molybdenum |
| title_sort | dinitrogen and organometallic chemistry of trimethylsilyl substituted triamidoamine complexes of molybdenum |
| topic | Chemistry. |
| url | http://hdl.handle.net/1721.1/50544 |
| work_keys_str_mv | AT odonoghuemyrabrigid1966 dinitrogenandorganometallicchemistryoftrimethylsilylsubstitutedtriamidoaminecomplexesofmolybdenum |