Observation of a Zundel-like transition state during proton transfer in hydroxide solutions

It is generally accepted that the anomalous diffusion of the aqueous hydroxide ion results from its ability to accept a proton from a neighboring water molecule; yet, many questions exist concerning the mechanism for this process. What is the solvation structure of the hydroxide ion? In what way do...

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Bibliographic Details
Main Authors: Tokmakoff, Andrei, Ramasesha, Krupa, Petersen, Poul B., Roberts, Sean Thomas, Martinez, Todd J., Ufimtsev, Ivan S.
Other Authors: Massachusetts Institute of Technology. Department of Chemistry
Format: Article
Language:en_US
Published: United States National Academy of Sciences 2010
Online Access:http://hdl.handle.net/1721.1/55305

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