Observation of a Zundel-like transition state during proton transfer in hydroxide solutions
It is generally accepted that the anomalous diffusion of the aqueous hydroxide ion results from its ability to accept a proton from a neighboring water molecule; yet, many questions exist concerning the mechanism for this process. What is the solvation structure of the hydroxide ion? In what way do...
Main Authors: | Tokmakoff, Andrei, Ramasesha, Krupa, Petersen, Poul B., Roberts, Sean Thomas, Martinez, Todd J., Ufimtsev, Ivan S. |
---|---|
Other Authors: | Massachusetts Institute of Technology. Department of Chemistry |
Format: | Article |
Language: | en_US |
Published: |
United States National Academy of Sciences
2010
|
Online Access: | http://hdl.handle.net/1721.1/55305 |
Similar Items
-
Proton Transfer in Concentrated Aqueous Hydroxide Visualized using Ultrafast Infrared Spectroscopy
by: Roberts, Sean Thomas, et al.
Published: (2012) -
The Dynamics of Aqueous Hydroxide Ion Transport Probed via Ultrafast Vibrational Echo Experiments
by: Roberts, Sean Thomas, et al.
Published: (2012) -
Structural Rearrangements in Water Viewed Through Two- Dimensional Infrared Spectroscopy
by: Roberts, Sean Thomas, et al.
Published: (2012) -
Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR
by: Nicodemus, Rebecca A., et al.
Published: (2012) -
A Source for Ultrafast Continuum Infrared and Terahertz Radiation
by: Petersen, Poul B., et al.
Published: (2012)