Spatially Extended Kondo State in Magnetic Molecules Induced by Interfacial Charge Transfer
An extensive redistribution of spin density in TBrPP-Co molecules adsorbed on a Cu(111) surface is investigated by monitoring Kondo resonances at different locations on single molecules. Remarkably, the width of the Kondo resonance is found to be much larger on the organic ligands than on the centra...
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| Eará dahkkit: | |
| Materiálatiipa: | Artihkal |
| Giella: | en_US |
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American Physical Society
2011
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| Liŋkkat: | http://hdl.handle.net/1721.1/60705 https://orcid.org/0000-0001-9342-0191 |
| _version_ | 1826193912230838272 |
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| author | Perera, U. G. E. Kulik, Heather Janine Iancu, V. Dias da Silva, L. G. G. V. Ulloa, S. E. Marzari, Nicola Hla, S. W. |
| author2 | Massachusetts Institute of Technology. Department of Materials Science and Engineering |
| author_facet | Massachusetts Institute of Technology. Department of Materials Science and Engineering Perera, U. G. E. Kulik, Heather Janine Iancu, V. Dias da Silva, L. G. G. V. Ulloa, S. E. Marzari, Nicola Hla, S. W. |
| author_sort | Perera, U. G. E. |
| collection | MIT |
| description | An extensive redistribution of spin density in TBrPP-Co molecules adsorbed on a Cu(111) surface is investigated by monitoring Kondo resonances at different locations on single molecules. Remarkably, the width of the Kondo resonance is found to be much larger on the organic ligands than on the central cobalt atom—reflecting enhanced spin-electron interactions on molecular orbitals. This unusual effect is explained by means of first-principles and numerical renormalization-group calculations highlighting the possibility to engineer spin polarization by exploiting interfacial charge transfer. |
| first_indexed | 2024-09-23T09:47:15Z |
| format | Article |
| id | mit-1721.1/60705 |
| institution | Massachusetts Institute of Technology |
| language | en_US |
| last_indexed | 2024-09-23T09:47:15Z |
| publishDate | 2011 |
| publisher | American Physical Society |
| record_format | dspace |
| spelling | mit-1721.1/607052022-09-26T13:43:30Z Spatially Extended Kondo State in Magnetic Molecules Induced by Interfacial Charge Transfer Perera, U. G. E. Kulik, Heather Janine Iancu, V. Dias da Silva, L. G. G. V. Ulloa, S. E. Marzari, Nicola Hla, S. W. Massachusetts Institute of Technology. Department of Materials Science and Engineering Marzari, Nicola Kulik, Heather Janine Marzari, Nicola An extensive redistribution of spin density in TBrPP-Co molecules adsorbed on a Cu(111) surface is investigated by monitoring Kondo resonances at different locations on single molecules. Remarkably, the width of the Kondo resonance is found to be much larger on the organic ligands than on the central cobalt atom—reflecting enhanced spin-electron interactions on molecular orbitals. This unusual effect is explained by means of first-principles and numerical renormalization-group calculations highlighting the possibility to engineer spin polarization by exploiting interfacial charge transfer. United States. Dept. of Energy (BES grant DE-FG02-02ER46012) National Science Foundation (U.S.) (NSF-PIRE-OISE 0730257) National Science Foundation (U.S.) (NSF-WMN 07010581) National Science Foundation (U.S.) (NSFDMR 0706020) United States. Army Research Office. Multidisciplinary University Research Initiative (MURI) (ARO-MURI DAAD-19-03-1-0169) 2011-01-25T19:33:25Z 2011-01-25T19:33:25Z 2010-09 2010-06 Article http://purl.org/eprint/type/JournalArticle 0031-9007 http://hdl.handle.net/1721.1/60705 Perera, U.G.E. et al. "Spatially Extended Kondo State in Magnetic Molecules Induced by Interfacial Charge Transfer." Physical Review Letters 105.10 (2010): 106601. © 2010 The American Physical Society https://orcid.org/0000-0001-9342-0191 en_US http://dx.doi.org/10.1103/PhysRevLett.105.106601 Physical Review Letters Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. application/pdf American Physical Society APS |
| spellingShingle | Perera, U. G. E. Kulik, Heather Janine Iancu, V. Dias da Silva, L. G. G. V. Ulloa, S. E. Marzari, Nicola Hla, S. W. Spatially Extended Kondo State in Magnetic Molecules Induced by Interfacial Charge Transfer |
| title | Spatially Extended Kondo State in Magnetic Molecules Induced by Interfacial Charge Transfer |
| title_full | Spatially Extended Kondo State in Magnetic Molecules Induced by Interfacial Charge Transfer |
| title_fullStr | Spatially Extended Kondo State in Magnetic Molecules Induced by Interfacial Charge Transfer |
| title_full_unstemmed | Spatially Extended Kondo State in Magnetic Molecules Induced by Interfacial Charge Transfer |
| title_short | Spatially Extended Kondo State in Magnetic Molecules Induced by Interfacial Charge Transfer |
| title_sort | spatially extended kondo state in magnetic molecules induced by interfacial charge transfer |
| url | http://hdl.handle.net/1721.1/60705 https://orcid.org/0000-0001-9342-0191 |
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