Large amplitude oscillatory shear of pseudoplastic and elastoviscoplastic materials

We explore the utility of strain-controlled large amplitude oscillatory shear (LAOS) deformation for identifying and characterizing apparent yield stress responses in elastoviscoplastic materials. Our approach emphasizes the visual representation of the LAOS stress response within the framework o...

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Main Authors: Ewoldt, Randy H., Winter, Peter, Maxey, Jason, McKinley, Gareth H.
Other Authors: Massachusetts Institute of Technology. Department of Mechanical Engineering
Format: Article
Language:en_US
Published: Springer Berlin / Heidelberg 2011
Online Access:http://hdl.handle.net/1721.1/61627
https://orcid.org/0000-0001-8323-2779
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author Ewoldt, Randy H.
Winter, Peter
Maxey, Jason
McKinley, Gareth H.
author2 Massachusetts Institute of Technology. Department of Mechanical Engineering
author_facet Massachusetts Institute of Technology. Department of Mechanical Engineering
Ewoldt, Randy H.
Winter, Peter
Maxey, Jason
McKinley, Gareth H.
author_sort Ewoldt, Randy H.
collection MIT
description We explore the utility of strain-controlled large amplitude oscillatory shear (LAOS) deformation for identifying and characterizing apparent yield stress responses in elastoviscoplastic materials. Our approach emphasizes the visual representation of the LAOS stress response within the framework of Lissajous curves with strain, strain-rate, and stress as the coordinate axes, in conjunction with quantitative analysis of the corresponding limit cycle behavior. This approach enables us to explore how the material properties characterizing the yielding response depend on both strain amplitude and frequency of deformation. Canonical constitutive models (including the purely viscous Carreau model and the elastic Bingham model) are used to illustrate the characteristic features of pseudoplastic and elastoplastic material responses under large amplitude oscillatory shear. A new parameter, the perfect plastic dissipation ratio, is introduced for uniquely identifying plastic behavior. Experimental results are presented for two complex fluids, a pseudoplastic shear-thinning xanthan gum solution and an elastoviscoplastic invert-emulsion drilling fluid. The LAOS test protocols and the associated material measures provide a rheological fingerprint of the yielding behavior of a complex fluid that can be compactly represented within the domain of a Pipkin diagram defined by the amplitude and timescale of deformation.
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spelling mit-1721.1/616272022-09-23T09:25:42Z Large amplitude oscillatory shear of pseudoplastic and elastoviscoplastic materials Ewoldt, Randy H. Winter, Peter Maxey, Jason McKinley, Gareth H. Massachusetts Institute of Technology. Department of Mechanical Engineering McKinley, Gareth H. Ewoldt, Randy H. Winter, Peter McKinley, Gareth H. We explore the utility of strain-controlled large amplitude oscillatory shear (LAOS) deformation for identifying and characterizing apparent yield stress responses in elastoviscoplastic materials. Our approach emphasizes the visual representation of the LAOS stress response within the framework of Lissajous curves with strain, strain-rate, and stress as the coordinate axes, in conjunction with quantitative analysis of the corresponding limit cycle behavior. This approach enables us to explore how the material properties characterizing the yielding response depend on both strain amplitude and frequency of deformation. Canonical constitutive models (including the purely viscous Carreau model and the elastic Bingham model) are used to illustrate the characteristic features of pseudoplastic and elastoplastic material responses under large amplitude oscillatory shear. A new parameter, the perfect plastic dissipation ratio, is introduced for uniquely identifying plastic behavior. Experimental results are presented for two complex fluids, a pseudoplastic shear-thinning xanthan gum solution and an elastoviscoplastic invert-emulsion drilling fluid. The LAOS test protocols and the associated material measures provide a rheological fingerprint of the yielding behavior of a complex fluid that can be compactly represented within the domain of a Pipkin diagram defined by the amplitude and timescale of deformation. National Science Foundation (U.S.) (Graduate Research Fellowship) United States. Defense Advanced Research Projects Agency (DARPA) (Chemical Robots program) 2011-03-08T14:04:11Z 2011-03-08T14:04:11Z 2009-12 2009-05 Article http://purl.org/eprint/type/JournalArticle 0035-4511 1435-1528 http://hdl.handle.net/1721.1/61627 Ewoldt, Randy et al. “Large amplitude oscillatory shear of pseudoplastic and elastoviscoplastic materials.” Rheologica Acta 49.2 (2010): 191-212. https://orcid.org/0000-0001-8323-2779 en_US http://dx.doi.org/10.1007/s00397-009-0403-7 Rheologica Acta Creative Commons Attribution-Noncommercial-Share Alike 3.0 http://creativecommons.org/licenses/by-nc-sa/3.0/ application/pdf Springer Berlin / Heidelberg MIT web domain
spellingShingle Ewoldt, Randy H.
Winter, Peter
Maxey, Jason
McKinley, Gareth H.
Large amplitude oscillatory shear of pseudoplastic and elastoviscoplastic materials
title Large amplitude oscillatory shear of pseudoplastic and elastoviscoplastic materials
title_full Large amplitude oscillatory shear of pseudoplastic and elastoviscoplastic materials
title_fullStr Large amplitude oscillatory shear of pseudoplastic and elastoviscoplastic materials
title_full_unstemmed Large amplitude oscillatory shear of pseudoplastic and elastoviscoplastic materials
title_short Large amplitude oscillatory shear of pseudoplastic and elastoviscoplastic materials
title_sort large amplitude oscillatory shear of pseudoplastic and elastoviscoplastic materials
url http://hdl.handle.net/1721.1/61627
https://orcid.org/0000-0001-8323-2779
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