An air-breathing, portable thermoelectric power generator based on a microfabricated silicon combustor

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, February 2011.

Bibliographic Details
Main Author: Marton, Christopher Henry
Other Authors: Klavs F. Jensen.
Format: Thesis
Language:eng
Published: Massachusetts Institute of Technology 2011
Subjects:
Online Access:http://hdl.handle.net/1721.1/62615
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author Marton, Christopher Henry
author2 Klavs F. Jensen.
author_facet Klavs F. Jensen.
Marton, Christopher Henry
author_sort Marton, Christopher Henry
collection MIT
description Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, February 2011.
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spelling mit-1721.1/626152019-04-10T09:17:30Z An air-breathing, portable thermoelectric power generator based on a microfabricated silicon combustor Marton, Christopher Henry Klavs F. Jensen. Massachusetts Institute of Technology. Dept. of Chemical Engineering. Massachusetts Institute of Technology. Dept. of Chemical Engineering. Chemical Engineering. Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, February 2011. This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections. "February 2011." Cataloged from student submitted PDF version of thesis. Includes bibliographical references (p. 224-237). The global consumer demand for portable electronic devices is increasing. The emphasis on reducing size and weight has put increased pressure on the power density of available power storage and generation options, which have been dominated by batteries. The energy densities of many hydrocarbon fuels exceed those of conventional batteries by several orders of magnitude, and this gap motivates research efforts into alternative portable power generation devices based on hydrocarbon fuels. Combustion-based power generation strategies have the potential to achieve significant advances in the energy density of a generator, and thermoelectric power generation is particularly attractive due to the moderate temperatures which are required. In this work, a portable-scale thermoelectric power generator was designed, fabricated, and tested. The basis of the system was a mesoscale silicon reactor for the combustion of butane over an alumina-supported platinum catalyst. The system was integrated with commercial bismuth telluride thermoelectric modules to produce 5.8 W of electrical power with a chemical-to-electrical conversion efficiency of 2.5% (based on lower heating value). The energy and power densities of the demonstrated system were 321 Wh/kg and 17 W/kg, respectively. The pressure drop through the system was 258 Pa for a flow of 15 liters per minute of air, and so the parasitic power requirement for air-pressurization was very low. The demonstration represents an order-of-magnitude improvement in portable-scale electrical power from thermoelectrics and hydrocarbon fuels, and a notable increase in the conversion efficiency compared with other published works. The system was also integrated with thermoelectric-mimicking heat sinks, which imitated the performance of high-heat-flux modules. The combustor provided a heat source of 206 to 362 W to the heat sinks at conditions suitable for a portable, air-breathing TE power generator. The combustor efficiency when integrated with the heat sinks was as high as 76%. Assuming a TE power conversion efficiency of 5%, the design point operation would result in thermoelectric power generation of 14 W, with an overall chemical-to-electrical conversion efficiency of 3.8%. by Christopher Henry Marton. Ph.D. 2011-05-09T14:01:24Z 2011-05-09T14:01:24Z 2010 2011 Thesis http://hdl.handle.net/1721.1/62615 717324172 eng M.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission. http://dspace.mit.edu/handle/1721.1/7582 247 p. application/pdf Massachusetts Institute of Technology
spellingShingle Chemical Engineering.
Marton, Christopher Henry
An air-breathing, portable thermoelectric power generator based on a microfabricated silicon combustor
title An air-breathing, portable thermoelectric power generator based on a microfabricated silicon combustor
title_full An air-breathing, portable thermoelectric power generator based on a microfabricated silicon combustor
title_fullStr An air-breathing, portable thermoelectric power generator based on a microfabricated silicon combustor
title_full_unstemmed An air-breathing, portable thermoelectric power generator based on a microfabricated silicon combustor
title_short An air-breathing, portable thermoelectric power generator based on a microfabricated silicon combustor
title_sort air breathing portable thermoelectric power generator based on a microfabricated silicon combustor
topic Chemical Engineering.
url http://hdl.handle.net/1721.1/62615
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